2,4,6,8-테트라메틸사이클로테트라실옥세인
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2,4,6,8-테트라메틸사이클로테트라실옥세인 속성
- 녹는점
- −69 °C(lit.)
- 끓는 점
- 134 °C(lit.)
- 밀도
- 0.986 g/mL at 25 °C(lit.)
- 증기압
- 0.05-479Pa at 20℃
- 굴절률
- n
20/D 1.387(lit.)
- 인화점
- 76 °F
- 저장 조건
- 2-8°C
- 물리적 상태
- 액체
- Specific Gravity
- 0.991
- 색상
- 무색 내지 거의 무색
- 수용성
- 대부분의 유기용매와 섞일 수 있습니다. 물과 섞이지 않습니다.
- 감도
- Moisture Sensitive
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 1787074
- InChIKey
- BQYPERTZJDZBIR-UHFFFAOYSA-N
- LogP
- -2.4-5.54 at 25℃
- CAS 데이터베이스
- 2370-88-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 10-36 | ||
안전지침서 | 16-26-36 | ||
유엔번호(UN No.) | UN 1993 3/PG 3 | ||
WGK 독일 | 3 | ||
F 고인화성물질 | 10-21 | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | III | ||
HS 번호 | 29319090 | ||
기존화학 물질 | 2010-3-4298 |
2,4,6,8-테트라메틸사이클로테트라실옥세인 C화학적 특성, 용도, 생산
개요
2, 4, 6, 8-TETRAMETHYLCYCLOTETRASILOXANE can be used as the precursor for the deposition of polysiloxane, cyclic siloxane, silicon dioxide, and gate dielectrics in thin-film transistors (TFT) (for example, for the preparation of ultralow dielectric constant pSiCOH film), and is a component of photochemically formed SiOX monolayers on TiO. It is a good impregnant of photoelectric material. It can be used for the manufacturing of modified siloxane with defined hydrogen content and chain quality.화학적 성질
Colorless or yellowish transparent liquid용도
2,4,6,8-Tetramethylcyclotetrasiloxane can occur addition reaction with unsaturated alkenes, so it’s utilized widely to synthesize variety functional reactive silicone fluids which is used to form silicone block copolymer, or used as crosslinker of vinyl addition silicone rubber. Tetramethyl-cyclotetrasiloxane is a good impregnant of photoelectric material. It is used to manufacture of modified siloxane with defined hydrogen content and chain quantity. It is also used in production of silicone polymers and acts as a precursor for the deposition of polysiloxane, cyclic siloxane, silicon dioxide, oxycarbide thin films with low dielectric constant for microelectronics and semiconductors.일반 설명
Atomic number of base material: 14 SiliconSynthesis
The synthesis process of 2,4,6,8-Tetramethylcyclotetrasiloxane is as follows. A 1-L four-necked flask equipped with a thermometer, stirrer, column packed with cylindrical glass of about 1x1 mm to a height of 500 mm, water-cooled condenser, outlet tube, and distillate receiver was connected to a vacuum pump. To the flask were fed 100 g of trimethylsiloxy end-capped dimethylpolysiloxane having a viscosity of 10,000 centistokes at 25°C and 1.0 g of the catalyst (i) synthesized above, after which agitation was commenced. While the flask interior was kept under a reduced pressure of 50 mmHg, the flask was heated at 250-260°C using a mantle heater. A fraction distilled out for 14 hours was collected (45 g). The residue (31 g) was a clear liquid. yeild= 52%참고 문헌
https://www.alfa.com/zh-cn/catalog/L16642/http://www.sigmaaldrich.com/catalog/product/aldrich/512990?lang=en®ion=US
Grill, A., and V. Patel. "Ultralow dielectric constant pSiCOH films prepared with tetramethylcyclotetrasiloxane as skeleton precursor." Journal of Applied Physics 104.2(2008):107.
Zhang, Jianming, D. S. Wavhal, and E. R. Fisher. "Mechanisms of SiO2 film deposition from tetramethylcyclotetrasiloxane, dimethyldimethoxysilane, and trimethylsilane plasmas." Journal of Vacuum Science & Technology A Vacuum Surfaces & Films 22.1(2004):201-213.
Fujino, Katsuhiro, et al. "Low-Temperature Atmospheric-Pressure Chemical Vapor Deposition, Using 2, 4, 6, 8-Tetramethylcyclotetrasiloxane and Ozone." Japanese Journal of Applied Physics 33. 4A (1994):2019-2024.
2,4,6,8-테트라메틸사이클로테트라실옥세인 준비 용품 및 원자재
원자재
준비 용품
2,4,6,8-테트라메틸사이클로테트라실옥세인 공급 업체
글로벌( 270)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Sirichem (Zhangjiakou) Sci-Tech.Co.,Ltd. | +8615831567206 |
China | 58 | 58 | |
Hubei Changfu Chemical Co., Ltd. | +86-027-84396550 +8617721064038 |
sales@cfsilanes.com | China | 401 | 58 |
Dongguan City Betterly New Materials co.,Ltd | +86-13713468294 +86-13535083564 |
waimaobu@betely.com | China | 37 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Jiangxi New jiayi New Materials Co., Ltd. | 15988280056 |
mina@xjysi.com | CHINA | 27 | 55 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 15928 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9348 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 |
kaia@neputrading.com | China | 1011 | 58 |
2,4,6,8-테트라메틸사이클로테트라실옥세인 관련 검색:
폴리(옥시(메틸실릴렌)) 테트라에텐일테트라메틸시클로테트라실록산 헵타메틸모노페닐시클로테트라실록산 시스-2,2,4,6,6,8-헥사메틸-4,8-디페닐사이클로테트라실록산 2,4,6,8-테트라메틸사이클로테트라실옥세인 옥타메틸시클로테트라실록산 2,4,6,8- 테트라 비닐 -2,4,6,8- 테트라 메틸 시클로 테트라 실록산
1,1,3,3-Tetramethyldisiloxane
Octaphenylcyclotetrasiloxane
1,3,5,7-TETRAKIS(3,3,3-TRIFLUOROPROPYL)1,3,5,7-TETRAMETHYLCYCLOSILOXANES
PLATINUM CARBONYL CYCLOVINYLMETHYLSILOXANE COMPLEX
Octaphenylsilsesquioxane
1,1,3,3-Tetramethyltetraphenylcyclotetrasiloxane
Platinate(2-),hexachloro-,dihydrogen,(OC-6-11)-,reactionproductswith2,4,6,8-tetraethenyl-2,4,6,8-tetramethylcyclotetrasiloxan
1,3,5,7,9,11,13-HEPTACYCLOPENTYL-15-GLYCIDYLPENTA-CYCLO[9.5.1.1(3,9).1(5,15).1(7,13)]OCTASILOXANE
1,3,5,7,9,11,14-HEPTACYCLOPENTYLTRICYCLO[7.3.3.1(5,11)]HEPTASILOXANE-ENDO-3,7,14-TRIOL
TETRAETHYLCYCLOTETRASILOXANE
2,4,6,8-tetrabutyl-2,4,6,8-tetramethylcyclotetrasiloxane