요오드화동(I)
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요오드화동(I) 속성
- 녹는점
- 605 °C (lit.)
- 끓는 점
- 1290 °C/1 atm (decomp)(lit.)
- 밀도
- 5.62 g/mL at 25 °C (lit.)
- 증기압
- 10 mm Hg ( 656 °C)
- 굴절률
- 2.346
- 인화점
- 1290°C
- 저장 조건
- Store below +30°C.
- 용해도
- 묽은 산 수용액: 불용성(lit.)
- 물리적 상태
- 가루
- Specific Gravity
- 5.62
- 색상
- 흰색에서 옅은 갈색까지
- 수용성
- 불용성
- 감도
- Air & Moisture Sensitive
- Crystal Structure
- Cubic, Sphalerite Structure - Space Group F(-4)3m
- Merck
- 14,2662
- Solubility Product Constant (Ksp)
- pKsp: 11.9
- 노출 한도
- ACGIH: TWA 1 mg/m3; TWA 0.01 ppm
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
- InChIKey
- LSXDOTMGLUJQCM-UHFFFAOYSA-M
- CAS 데이터베이스
- 7681-65-4(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn,N,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 22-36/37/38-50/53 | ||
| 안전지침서 | 22-24/25-26-61-57-37/39-29 | ||
| 유엔번호(UN No.) | UN 3077 9/PG 3 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 8 | ||
| TSCA | Yes | ||
| 위험 등급 | 9 | ||
| HS 번호 | 28276000 | ||
| 유해 물질 데이터 | 7681-65-4(Hazardous Substances Data) | ||
| 기존화학 물질 | KE-08941 |
요오드화동(I) C화학적 특성, 용도, 생산
용도
금속화합물, 의약품, 사료첨가제, 유기반응촉매, 살균용도
여러 유기반응에 촉매로 쓰이며, 동물사료의 아이오딘 공급원, 인공강우를 위한 구름 형성의 핵, 음극선관의 도장제·살균제 등으로 용도가 다양하다.화학적 성질
Cuprous Iodide, Cu2O, cubic white crystals, practically insoluble in H2O or alcohol, soluble in NH4OH, potassium iodide, or potassium cyanide. Used in Sandmeyer’s reaction to synthesize aryl chlorides.용도
Copper (I) Iodide used in the preparation of alkynyl imines and the synthesis of pyrroles and pyrrole heterocycles. It is also used in the synthesis of BTBT derivatives ([1]Benzothieno[3,2-b]benzothio phene) for use as semiconductors in transistors.일반 설명
Odorless tan or off-white solid. Sinks in water.반응 프로필
Cuprous iodide has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.위험도
Toxic.건강위험
Inhalation causes irritation of nose and throat. Ingestion of copper salts produces violent vomiting and purging, intense pain, collapse, coma, convulsions, and paralysis. Contact with eyes or skin causes irritation.화재위험
Special Hazards of Combustion Products: Irritating hydrogen iodide or iodine vapors may form in fire.Purification Methods
It can be freshly prepared by dissolving an appropriate quantity of CuI in boiling saturated aqueous NaI over 30minutes. Pure CuI is obtained by cooling and diluting the solution with water, followed by filtering and washing sequentially with H2O, EtOH, EtOAc, Et2O and pentane, then drying in vacuo for 24hours [Dieter, J Am Chem Soc 107 4679 1985]. Alternatively wash it with H2O, then EtOH and finally with Et2O containing a little iodine. Traces of H2O are best removed first by heating at 110o and then at 400o. Exess of I2 is removed completely at 400o. It dissolves in Et2O if an amine is present to form the amine complex. On heating it becomes red, then black, but changes to white on cooling. It is sparingly soluble in H2O or alkali iodide solutions but readily soluble in NH3 (which absorbs CO) and in cyanide or thiosulfate solutions. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed Brauer) Academic Press Vol II p 1007 1965, Bawn & Ledwith Chem Ind (London) 1180 1957.]요오드화동(I) 준비 용품 및 원자재
원자재
준비 용품
5-(2-PHENYLETH-1-YNYL)THIOPHENE-2-CARBALDEHYDE
4-(트리플루오로메틸)피리딘-3-카복실산
4-ETHYNYLANILINE
(트리 플루오로 메틸) 트리메틸 실란
4-(이미다졸-1-일)페놀
6-MORPHOLINONICOTINOYL CHLORIDE
6-MORPHOLINONICOTINIC ACID
METHYL 4-AMINO-6-INDOLECARBOXYLATE
4-Azaindole
4-Nitrophenylboronic acid
1-phenyl-3-(trifluoromethyl)pyrazole-4-carboxylic acid
3-IODO-2-NITROPYRIDINE
4-Phenylpyridine
2-CHLORO-4-NITROBENZOTRIFLUORIDE
3-PHENOXYPHENYLACETIC ACID
1-[6-(Trifluoromethyl)pyridin-2-yl]piperazine
2-Fluoro-4-(methylsulfonyl)aniline
N,N-DIPHENYLQUINACRIDONE
4-PHENYLETHYNYLPHTHALIC ANHYDRIDE
(+)-DISPARLURE
Diphenylacetylene
2-Chloro-6-trifluoromethylnicotinic acid
1-(3-AMINO-PYRIDIN-2-YL)-ETHANONE
2-Trifluoromethyl-5-bromopyridine
4-AMINO-2-CHLOROBENZOTRIFLUORIDE
2-(TRIFLUOROMETHYL)-4-ISOCYANATOPYRIDINE
2-Trifluoromethyl-6-pyridinecarboxylic acid
6-(TRIFLUOROMETHYL)PYRIDINE-3-CARBOXALDEHYDE
2-(TRIFLUOROMETHYL)-PYRIDINE-4-CARBOXALDEHYDE
요오드화동(I) 공급 업체
글로벌( 596)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 5993 | 58 |
| Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5964 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 7845 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9348 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |