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ChemicalBook >제품 카탈로그 >(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 구조식 이미지
카스 번호:
380230-02-4
상품명:
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
동의어(영문):
3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
CBNumber:
CB5190531
분자식:
C36H30NO2P
포뮬러 무게:
539.6
MOL 파일:
380230-02-4.mol
MSDS 파일:
SDS

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 속성

녹는점
88-89 °C
끓는 점
710.7±63.0 °C(Predicted)
알파
+13.1° (c 1.01, CHCl3)
저장 조건
under inert gas (nitrogen or Argon) at 2-8°C
산도 계수 (pKa)
-0.57±0.20(Predicted)
물리적 상태
가루
색상
회백색
감도
moisture sensitive
InChIKey
LKZPDRCMCSBQFN-UIOOFZCWSA-N

안전

위험 카페고리 넘버 36/37/38
안전지침서 26-36/37/39
WGK 독일 3

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) C화학적 특성, 용도, 생산

용도

The product may be used as a ligand in:
  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 준비 용품 및 원자재

원자재

준비 용품

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 공급 업체

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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 관련 검색:

(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
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