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2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE 구조식 이미지

카스 번호:: 82495-75-8

상품명:: 2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE

동의어(영문):: PHENYL PHOSPHONIUM CHLORIDE;SEM-TRIPHENYLPHOSPHONIUM CHLORIDE;triphenyl(2-trimethylsilylethoxymethyl)phosphanium;[2-(trimethylsily)ethoxymethyl]triphenylphosphonium.Cl;2-(trime-silyl)ethoxymethyl-triphenyl-phosphonium chloride;-(Trimethylsilyl)ethoxymethyl-triphenylphosphonium chloride;2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE;triphenyl(2-trimethylsilylethoxymethyl)phosphanium:chloride;Triphenyl((2-(trimethylsilyl)ethoxy)methyl)phosphonium chloride;Phosphonium, triphenyl[[2-(trimethylsilyl)ethoxy]methyl]-, chloride

CBNumber:: CB6125466

분자식:: C24H30ClOPSi

포뮬러 무게:: 429.01

MOL 파일:: 82495-75-8.mol

속성

안전

용도

공급 업체 72

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE 속성

녹는점: 145-149 °C(lit.)

저장 조건: Sealed in dry,2-8°C

용해도: Sol H2O and dichloromethane; sparingly soluble in THF.

물리적 상태: powder to crystal

색상: 흰색에서 거의 흰색

BRN: 4632507

CAS 데이터베이스: 82495-75-8(CAS DataBase Reference)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	Xi
위험 카페고리 넘버	36/37/38
안전지침서	26-36
WGK 독일	3
F 고인화성물질	3
HS 번호	2931.90.6000

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H315	피부에 자극을 일으킴	피부부식성 또는 자극성물질	구분 2	경고	P264, P280, P302+P352, P321,P332+P313, P362
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고	P264, P280, P305+P351+P338,P337+P313P
H335	호흡 자극성을 일으킬 수 있음	특정 표적장기 독성 - 1회 노출;호흡기계 자극	구분 3	경고

예방조치문구:

P261	분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P305+P351+P338	눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

NFPA 704

	0
2		0

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE C화학적 특성, 용도, 생산

물리적 성질

mp 165–169 °C.

용도

2-(Trimethylsilyl)ethoxymethyltriphenylphosphonium Chloride is used in preparation of Benzodecalindiones as antitumor agents.

제조 방법

Involves reaction of triphenylphosphine with 2-(trimethylsilyl)ethoxymethyl chloride in benzene at gentle reflux for 18 h. Upon cooling, the resulting phosphonium salt can be recovered by filtration and purified by triturating with diethyl ether in 94% yield.

Purification Methods

Wash the solid with AcOH and recrystallise it from CH2Cl2/EtOAc. Dry it in a vacuum desiccator. Hygroscopic. 1H NMR (CDCl3) : -0.2 (s, Me3Si), 0.8 (t, 8Hz, CH2Si), 3.83 (t, 8Hz, OCH2), 5.77 (d, JPH 4Hz, P+-CH2O) and 7.70 (m, aromatic H). [Sch.nauer & Zbiral Justus Liebigs Ann Chem 1039 1983.]

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE 준비 용품 및 원자재

원자재

준비 용품

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE 공급 업체

글로벌( 72)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Career Henan Chemica Co	+86-0371-86658258 15093356674;	laboratory@coreychem.com	China	30255	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	57511	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131981	58
Mainchem Co., Ltd.	+86-0592-6210733	sale@mainchem.com	China	32360	55

2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE 관련 검색:

트라이메틸실레인 [Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I),98% Triphenylphosphine hydrobromide Triphenylacetic acid Triphenylmethyl Chloride Triphenylphosphine oxide Chlorotriphenyltin TRIPHENYL BORATE Bis(triphenylphosphinepalladium) acetate Triphenylmethane Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE N-BOC-IMINO-(TRIPHENYL)PHOSPHORANE HYDROXYMETHYL TRIPHENYLPHOSPHONIUM CHLORIDE 2-(Trimethylsilyl)ethanol 2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE (Methoxymethyl)triphenylphosphonium chloride