테트라플루오르붕산 은
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테트라플루오르붕산 은 속성
- 녹는점
- 70-73 °C(lit.)
- 저장 조건
- Store below +30°C.
- 용해도
- Acetonitrile (Slightly), Methanol (Very Slightly)
- 물리적 상태
- 결정성 분말
- 색상
- 흰색에서 옅은 갈색까지
- 수용성
- 녹는
- 감도
- Hygroscopic
- 노출 한도
- ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
- InChIKey
- CCAVYRRHZLAMDJ-UHFFFAOYSA-N
- CAS 데이터베이스
- 14104-20-2(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | C | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 34-22-20/21/22 | ||
| 안전지침서 | 26-36/37/39-45-27 | ||
| 유엔번호(UN No.) | UN 3260 8/PG 2 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | ED2875000 | ||
| F 고인화성물질 | 3-8-10-21 | ||
| 위험 참고 사항 | Corrosive | ||
| TSCA | T | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | III | ||
| HS 번호 | 28432900 | ||
| 기존화학 물질 | KE-31290 | ||
| 유해화학물질 필터링 | 97-1-92 | ||
| 함량 및 규제정보 | 물질구분: 유독물질; 혼합물(제품)함량정보: 무기은 염류 및 이를 25% 이상 함유한 혼합물. 다만, 염화 은(Silver chloride) 및 뇌산 은(Silver fulminate)은 제외 |
테트라플루오르붕산 은 C화학적 특성, 용도, 생산
화학적 성질
beige crystalline powder용도
Silver tetrafluoroborate finds applications as a useful reagent in inorganic, organic and organomettalic chemistry. It acts as a moderately strong oxidant in dichloromethane, replaces halide anions and ligands with weakly coordinating tetrafluoroborate anions, and behaves as a catalyst for cyclization reactions. It is a potent promoter for chemical glycosylation.주요 응용
Silver tetrafluoroborate is a transition metal salt extensively used in organic syntheses.Gold Catalysts — 21st Century ′Gold Rush′
Displaces chloride from precious metal complexes used in the oxidation of alcohols by persulfate.
Provides a silver-ion template for improved macrolatamization of a linear dipeptide.
일반 설명
Silver tetrafluoroborate (AgBF4) is used as a Lewis acid in organic synthesis. It is known to have a high affinity towards organic halides. It is employed in organic reactions like activation of acyl chlorides, nucleophilic substitution, rearrangement, cycloaddition, cyclization, ring expansion and oxidation.Safety Profile
Poison by intravenous route. When heated to decomposition it emits toxic fumes of F-. Used for plating baths. See also SILVER COMPOUNDS, BORON COMPOUNDS, and FLUORIDES.Synthesis
Preparation of silver tetrafluoroborate and MBDPThis reaction is completed with the lights off. In a 25 mL round-bottom flask covered with aluminum foil, AgBF4 (0.0397 g (0.20 mmol) is dissolved in 10 mL CH3CN. To the solution MBDP (0.0645 g, 0.20 mmol) is added and allowed to stir for 3 hours. The solution is concentrated under vacuum to approximately 3 mL then layered with Et2O. The flask is placed in the freezer. X-ray quality crystals are formed.
테트라플루오르붕산 은 준비 용품 및 원자재
원자재
준비 용품
테트라플루오르붕산 은 공급 업체
글로벌( 210)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 |
jack.li@time-chemicals.com | China | 1807 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
| Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com |
jocelynpan@zjarts.com | CHINA | 993 | 58 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49390 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9641 | 58 |
| Hubei Ipure Biology Co., Ltd | +8613367258412 |
ada@ipurechemical.com | China | 10326 | 58 |
| Shanghai Bosheng Metal Materials Co. LTD | 18601346310 |
CHINA | 153 | 58 |