N-니트로소디-N-프로필아민

N-니트로소디-N-프로필아민
N-니트로소디-N-프로필아민 구조식 이미지
카스 번호:
621-64-7
한글명:
N-니트로소디-N-프로필아민
동의어(한글):
니트로소디프로필아민;N-나이트로소디-N-프로필아민;N-니트로소디-N-프로필아민;나이트로소다이프로필아민
상품명:
N-NITROSODI-N-PROPYLAMINE
동의어(영문):
DPNA;NSC 133;rcrawastenumberu111;DIPROPYLNITROSAMINE;nitrosodipropylamin;Nitrosodipropylamine;nitrous dipropylamide;Di-n-prpylnitrosamine;Di-N-propylnitrosamine;dipropyl-nitroso-amine
CBNumber:
CB7400641
분자식:
C6H14N2O
포뮬러 무게:
130.19
MOL 파일:
621-64-7.mol
MSDS 파일:
SDS

N-니트로소디-N-프로필아민 속성

끓는 점
113 °C / 40mmHg
밀도
0.92
굴절률
1.4468 (589.3 nm 20℃)
인화점
10 °C
저장 조건
Inert atmosphere,2-8°C
용해도
에탄올과 에테르에 매우 잘 용해됨(인용, Keith and Walters, 1992)
산도 계수 (pKa)
-3.18±0.70(Predicted)
색상
노란색에서 금색의 액체
수용성
25°C에서 9,900mg/L (Mirvish et al., 1976)
IARC
2B (Vol. 17, Sup 7) 1987
EPA
N-Nitrosodi-n-propylamine (621-64-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,F
위험 카페고리 넘버 45-22-51/53-39/23/24/25-23/24/25-11
안전지침서 53-45-61-36/37-16
유엔번호(UN No.) 2810
WGK 독일 3
RTECS 번호 JL9700000
HS 번호 2921.29.0055
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 621-64-7(Hazardous Substances Data)
독성 Acute oral LD50 for rats 480 mg/kg (quoted, RTECS, 1985).
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H350 암을 일으킬 수 있음 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 1A, 1B 위험 GHS hazard pictograms
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
1
2 0

N-니트로소디-N-프로필아민 C화학적 특성, 용도, 생산

화학적 성질

N-nitrosodi-N-propylamine is a yellow liquid.

용도

N-Nitrosodi-n-propylamine is used in small quantities in laboratory research. It has no known commercial use (IARC 1978, ATSDR 1989, HSDB 2009).

일반 설명

Clear to pale yellow liquid.

반응 프로필

N-NITROSODI-N-PROPYLAMINE is a nitrated amine derivative. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

건강위험

ACUTE/CHRONIC HAZARDS: Toxic.

화재위험

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic data. Moderately toxic by ingestion and subcutaneous routes. An experimental teratogen. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITROSAMINES.

잠재적 노출

N-nitrosodi-N-propylamine is used in the manufacture of plastics, resins, rubber, and synthetic textiles. There is no evidence that N-nitrosodi-N-propylamine exists naturally in soil, air, food, or water. Small quantities of N-nitrosodi-N-propylamine are inadvertently produced during some manufacturing processes; as an impurity in some commercially available dinitroaniline based weed killers, and during the manufacture of some rubber products. However, according to Sax, some similar N-nitroso compounds are formed in the environment and absorbed from precursors in food, water, or air; from tobacco; and from naturally occurring compounds.

Carcinogenicity

N-Nitrosodi-n-propylamine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

환경귀착

Chemical/Physical. N-Nitroso-n-propylamine will not hydrolyze because it does not contain a hydrolyzable functional group (Kollig, 1993).
At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 24, 13, 7.4, and 4.0 mg/g, respectively (Dobbs and Cohen, 1980).

운송 방법

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard Class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Sensitive to UV light.

폐기물 처리

N-Nitrosodi-N-propylamine may be destroyed by high temperature incineration in an incinerator equipped with an nitrogen oxide scrubber. Chemical treatment methods may also be used to destroy N-nitrosodi-N-propylamine. These methods involve (a) denitrosation by reaction with 3% hydrobromic acid in glacial acetic acid; (b) oxidation by reaction with potassium permanganate-sulfuric acid; or (c) extraction of the nitrosamine from the waste using dichloromethane and subsequent reaction with triethyloxonium tetrafluoroborate (TOEF). Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

N-니트로소디-N-프로필아민 준비 용품 및 원자재

원자재

준비 용품


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