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트리페닐아민

트리페닐아민
트리페닐아민 구조식 이미지
카스 번호:
603-34-9
한글명:
트리페닐아민
동의어(한글):
트라이페닐아민;트라이페닐아민(트리페닐아민);트리페닐아민;트리페닐아민
상품명:
Triphenylamine
동의어(영문):
Three aniline;Triphenylamin;TRIPHENYLAMINE;amine,triphenyl;Trisphenylamine;Triphenylamine99+%;Triphenylamine,98%;Triphenylamine >N,N-DIPHENYLANILINE;Trisphenylamine 98%
CBNumber:
CB9401415
분자식:
C18H15N
포뮬러 무게:
245.32
MOL 파일:
603-34-9.mol

트리페닐아민 속성

녹는점
124-128 °C (lit.)
끓는 점
347-348 °C (lit.)
밀도
0.7740
굴절률
1.3530 (estimate)
인화점
365°C
저장 조건
Sealed in dry,Room Temperature
산도 계수 (pKa)
-3.04±0.30(Predicted)
물리적 상태
Crystalline Powder
색상
Off-white to slightly beige
수용성
insoluble
BRN
2050487
안정성
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS 데이터베이스
603-34-9(CAS DataBase Reference)
NIST
Benzenamine, N,N-diphenyl-(603-34-9)
EPA
Triphenylamine (603-34-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/38-36/37/38-38-36
안전지침서 26-28-37/39-26,37/39
WGK 독일 2
RTECS 번호 YK2680000
위험 참고 사항 Irritant
TSCA Yes
HS 번호 29214980
유해 물질 데이터 603-34-9(Hazardous Substances Data)
기존화학 물질 KE-05-1332
그림문자(GHS):
신호 어:
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
1 0

트리페닐아민 MSDS


N,N-diphenylbenzenamine

트리페닐아민 C화학적 특성, 용도, 생산

화학적 성질

Monoclinic crystals from EtOAc.

화학적 성질

Triphenylamine is a colorless crystalline solid.

용도

Organic light-emitting diode (OLED) devices have received much attention, because they are expected to be a next generation display and light source, thanks to lightweight and flexible organic materials.
  1. Triphenylamine is a propeller-like structural chromophore with a nitrogen atom center. The compound has a large steric hindrance and hyper conjugation electronic effect, which can enhance the stability of the nitrogen atomic radical. Triphenylamine materials also have a high hole mobility due to their unique free radicals nature. Many hole transport materials based on triphenylamine derivatives (TPD) are widely usable,because they are heat-resistant and amorphous.In addition to the TPDs, oxadiazole derivatives (PBD) having an electron transport property, Alq3 as a host material,and blue emissive distylyl derivatives are fundamental materials for amorphous OLED devices.
  2. It is used in the manufacture of photographic film.
  3. Triphenylamines (TPAs) are highly fluorescent compounds that are efficient to induce cell death upon visible light excitation.
  4. Triphenylamine is used in organic light-emitting diode as hole-transporters and as a pharmaceutical intermediate.
  5. It is coated on film bases as primary photoconductor.

용도

It is coated on photographic film, where it acts as photoconductor.

용도

Triphenylamine is used in organic light-emitting diode as hole-transporters and as a pharmaceutical intermediate. It is coated on film bases as primary photoconductor.

Synthesis Reference(s)

Canadian Journal of Chemistry, 61, p. 86, 1983 DOI: 10.1139/v83-015
Organic Syntheses, Coll. Vol. 1, p. 544, 1941

공기와 물의 반응

Insoluble in water.

반응 프로필

Triphenylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

건강위험

Triphenyl amine is considered to have low systemic toxicity, but it may act as a slight skin irritant. Adverse effects have not been reported in humans.

화재위험

The flash point of Triphenylamine has not been determined, but Triphenylamine is probably combustible.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also AROMATIC AMINES.

잠재적 노출

Triphenylamine is used as a primary photoconductor and in making photographic film coated on photographic film bases.

Carcinogenicity

Triphenyl amine was not mutagenic in bacterial assays with or without metabolic activation.

Purification Methods

Crystallise the amine from EtOH or from *benzene/absolute EtOH, diethyl ether and pet ether. It is sublimed under vacuum and carefully dried in a vacuum line. Store it in the dark under nitrogen. [Beilstein 12 IV 276.]

비 호환성

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxo acids, epoxides, aldehydes, ketones.

트리페닐아민 준비 용품 및 원자재

원자재

준비 용품


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