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ChemicalBook >> CAS DataBase List >>FUMING SULFURIC ACID

FUMING SULFURIC ACID suppliers

FUMING SULFURIC ACID

CAS:
8014-95-7
MF:
H2O7S2
MW:
178.14

Company Type

Properties

Melting point:
2 °C
Boiling point:
~290 °C(lit.)
Density 
1.925 g/mL at 25 °C(lit.)
vapor density 
<0.3 (25 °C, vs air)
vapor pressure 
1 mm Hg ( 146 °C)
storage temp. 
Store below +30°C.
solubility 
H2O: soluble
pka
1.92(at 25℃)
form 
Liquid
color 
Colorless
Specific Gravity
1.925
PH
<1 (100g/l, H2O, 20℃)
Water Solubility 
Miscible with water.
Sensitive 
Hygroscopic
Merck 
14,8974
BRN 
2037554
Exposure limits
ACGIH: TWA 0.2 mg/m3
OSHA: TWA 1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 1 mg/m3
Dielectric constant
84(20.0℃)
Stability:
Stable. Incompatible with organic materials, powdered metals, bases, halides. Reacts violently with water. Very hygroscopic.

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word 
Danger
Hazard statements 
H314-H330-H335
Precautionary statements 
P260-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes 
C
Risk Statements 
36/38-37-35-14-34
Safety Statements 
26-30-45-36/37/39
RIDADR 
UN 3264 8/PG 3
WGK Germany 
1
RTECS 
WS5600000
3
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28070000

Use

Fumes in air. Soluble in water; dissolution generates dangerous amounts of heat that can cause localized boiling and spattering of the acidic mixture and generate heavy fumes. During sulfonation of mononitrobenzene with fuming sulfuric acid, a leak from an internal cooling coil permitted water to enter the reaction tank. A violent eruption occurred due to the heat of solution [MCA Case History 944(1963)].

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