L-ABRINE suppliers
L-ABRINE
- CAS:
- 526-31-8
- MF:
- C12H14N2O2
- MW:
- 218.25
Suppliers by country/region
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Properties
- Melting point:
- >300 °C (dec.)(lit.)
- alpha
- D21 +44° (0.28 g in 10 ml 0.5N HCl)
- Boiling point:
- 358.94°C (rough estimate)
- Density
- 1.272±0.06 g/cm3 (20 ºC 760 Torr)
- refractive index
- 65 ° (C=1, 0.5mol/L NaOH)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- H2O : 2 mg/mL (9.16 mM; ultrasonic and adjust pH to 10 with NaOH)
- form
- Cryst.
- pka
- 2.32±0.10(Predicted)
- optical activity
- [α]20/D +65°, c = 1 in 0.5 M NaOH
- Merck
- 14,10
- BRN
- 86638
Safety Information
- Symbol(GHS)
GHS07
- Signal word
- Warning
- Hazard statements
- H302+H312+H332
- Precautionary statements
- P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22
- Safety Statements
- 36
- WGK Germany
- 3
- HS Code
- 29339900
Use
Crystallise L-abrine from H2O or EtOH/H2O mixture and dry it for 2days at 60o in high vacuum; it has m 275-290o(dec with browning at 230o) and [] D +47.2o (c 2, 0.5N HCl) [Peter et al. Helv Chim Acta 46 577 1963]. [Gregory & Morley J Chem Soc 913 1968, Beilstein 22/14 V 40.]
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