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(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane

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(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane Basic information
Product Name:(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane
Synonyms:(R)-2,2-DIMETHYL-4-HYDROXYETHYL-[1,3]DIOXOLANE;2(2,2-DIMETHYL-[1,3] DIOXOLAN-4-YL)-ETHANOL (R);(4R)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,&;(R)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)ethanol;(R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane;(R)-1,2-ISOPROPYLIDENEBUTANE-1,2,4-TRIOL;(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 96%;(R)-1,2-O-Isopropylidenebutane-1,2,4-triol
CAS:70005-89-9
MF:C7H14O3
MW:146.18
EINECS:
Product Categories:Chiral Building Blocks;Dioxanes & Dioxolanes;Dioxolanes;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Alcohols;Chiral Building Blocks;Organic Building Blocks
Mol File:70005-89-9.mol
(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane Structure
(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane Chemical Properties
Boiling point 207 °C(lit.)
density 1.045 g/mL at 25 °C(lit.)
refractive index n20/D 1.4390(lit.)
Fp 224 °F
storage temp. Storage temp. 2-8°C
pka14.80±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Optical RotationConsistent with structure
InChI1S/C7H14O3/c1-7(2)9-5-6(10-7)3-4-8/h6,8H,3-5H2,1-2H3/t6-/m1/s1
InChIKeyYYEZYENJAMOWHW-ZCFIWIBFSA-N
SMILESCC1(C)OC[C@@H](CCO)O1
CAS DataBase Reference70005-89-9
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29329990
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane Usage And Synthesis
Uses(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane can be used:
  • To introduce a chiral center selectively in the carbon chain C10 during the total synthesis of protectin D1.
  • As a starting material in the total synthesis of an anti-diabetic molecule cytopiloyne.
  • As a starting material in the preparation of 4-15N-amino-2-butane-1,2-diol, which is used to synthesize 15N-labeled oligodeoxynucleotides.

(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane Preparation Products And Raw materials
Tag:(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane(70005-89-9) Related Product Information
Diacetone-D-glucose 2',3'-O-Isopropylideneadenosine (+)-5,6-O-Isopropylidene-L-ascorbic acid 2′,3′-O-Isopropylideneuridine fluocinolone16,17-acetonide Methyl 2,3-O-isopropylidene-5-O-(p-tolylsulfonyl)-beta-D-ribofuranoside 2',3'-O-Isopropylideneinosine Methyl-2,3-O-isopropylidene-D-ribofuranoside 5'-Acetyl-2',3'-isopropylideneadenosine 1,6-Anhydro-3,4-O-isopropylidene-2-tosyl-β-D-galactopyranose 6-Deoxy-1,2:3,4-di-O-isopropylidene-6-iodo-ALPHA-D-galactopyranose 1,2:5,6-Di-O-isopropylidene-alpha-D-ribo-3-hexulofuranose (4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane 2',3'-O-Isopropylidene-5'-tritylinosine 5-O-Carbomethoxy-1,2-O-isopropylidene-D-xylofuranose 6-O-Acetyl-1,2:3,4-di-O-isopropylidene-alpha-D-galactopyranose 5-O-Carbomethoxy-1,2-O-iso-propylidene-3-O-(p-tolyl-sulfonyl)-alpha-D-xylofuranose