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Ytterbium(III) oxide

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CAS:1314-37-0
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Ytterbium(III) oxide Basic information
Description References
Product Name:Ytterbium(III) oxide
Synonyms:Ytterbium(III) oxide, REacton, 99.998% (REO);Ytterbium (III) oxide, 99,999%;Ytterbium(III) oxide, REacton, 99.9% (REO);Ytterbium(III) oxide, REacton, 99.99% (REO);Ytterbium(III) oxide, 99.9% (REO);Ytterbium(III) oxide, REacton(R), 99.99% (REO);Ytterbium(III) oxide, REacton(R), 99.998% (REO);Ytterbium(III) oxide, REacton(R), 99.9% (REO)
CAS:1314-37-0
MF:O3Yb2
MW:394.08
EINECS:215-234-0
Product Categories:metal oxide;70: Yb;Nanoparticles: Oxides, Nitrides, and Other CeramicsChemical Synthesis;YtterbiumNanomaterials;Catalysis and Inorganic Chemistry;Materials Science;Nanomaterials;Nanopowders and Nanoparticle Dispersions;Oxides;YtterbiumMetal and Ceramic Science;Chemical Synthesis;Ytterbium;Inorganics;Boron, Nitrile, Thio,& TM-Cpds
Mol File:1314-37-0.mol
Ytterbium(III) oxide Structure
Ytterbium(III) oxide Chemical Properties
Melting point 2227°
density 9.17g/mLat25°C(lit.)
storage temp. no restrictions.
solubility soluble in dilute acid solutions
form powder
Specific Gravity9.17
color White
Water Solubility Soluble in hot dilute acids. Insoluble in water.
Crystal StructureCubic
Merck 14,10105
crystal systemCube
Space groupIa3
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.04341.04341.04349090901.1359
InChIKeyFIXNOXLJNSSSLJ-UHFFFAOYSA-N
CAS DataBase Reference1314-37-0(CAS DataBase Reference)
EPA Substance Registry SystemYtterbium oxide (Yb2O3) (1314-37-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
HS Code 28469019
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Ytterbium(III) oxide Usage And Synthesis
DescriptionYtterbium oxide is the oxide product of the rare earth metal element ytterbium. It can be used in thermal shielding coating materials, electronic materials, active device materials, battery materials and bio-pharmaceuticals. It is also applied to fiber amplifier and fiber optic technologies and in lasing applications. The spectral emissivity of ytterbium oxide-based materials also makes it be used as selective emitter in thermophotovoltaic devices.
ReferencesErbium oxide/ytterbium oxide doped glass lasers: U.S. Patent 3,663,474[P]. 1972-5-16.
Mao, Y., and J. P. Chang. "Erbium and/or Ytterbium Doped Yttrium Oxide Nanotubes for Optical Amplifier Application.".
Krishna, M Ghanashyam, et al. "Spectral emissivity of ytterbium oxide-based materials for application as selective emitters in thermophotovoltaic devices." Solar Energy Materials & Solar Cells 59.4(1999):337-348.
Haumesser, Paul Henri, et al. "Determination of laser parameters of ytterbium-doped oxide crystalline materials." Journal of the Optical Society of America B 19.10(2002):2365-2375.
Chemical PropertiesYtterbium (III) oxide is white powder and pieces, has no odour, is insoluble in water, and is incompatible with strong acids, oxidising agents, and carbon dioxide.
Physical propertiesColorless cubic crystals when pure; tinted brown or yellowish white in presence of thulia; density 9.17 g/cm3; insoluble in water; soluble in hot dilute acids.
UsesYtterbium oxide (Yb2O3) is used to make special alloys, ceramics, and glass. It can be used for carbon arc-lamp electrodes that produce a very bright light.
UsesYtterbium(III) oxide is being applied to numerous fiber amplifier and fiber optic technologies. High purity Ytterbium Oxide are widely applied as a doping agent for garnet crystals in lasers a important colorant in glasses and porcelain enamel glazes.. As Ytterbium Oxide has a significantly higher emissivity in the infrared range a higher radiant intensity is obtained with Ytterbium-based payloads.
PreparationYtterbium oxide is produced as an intermediate in recovering ytterbium from minerals (See Ytterbium). After opening the ore by digestion with concentrated sulfuric acid or caustic soda solution at high temperatures, rare earths are separated by ion exchange, solvent extraction, or fractional precipitation. Ytterbium fraction is treated with oxalic acid or sodium oxalate to precipitate ytterbium oxalate, which is ignited to yield ytterbium oxide.
ApplicationYtterbium(III) oxide (Yb2O3) is a versatile buffer material for applications in perovskite solar cells (PSCs). The application of this ytterbium oxide buffer material to pi-n PSCs with narrow bandgap packet absorbers resulted in certified power conversion efficiencies in excess of 25%. The broad applicability of Yb2O3 in achieving efficient PSCs using various types of phosphor absorber layers was also demonstrated, with efficiencies of 20.1% and 22.1% achieved for wide bandgap phosphor absorber and medium bandgap phosphor absorber layers, respectively. In addition, the stability of ytterbium oxide packaged devices is significantly enhanced after ISOS-L-3 accelerated aging.
Flammability and ExplosibilityNot classified
Ytterbium(III) oxide Preparation Products And Raw materials
Raw materialsMISCH METAL-->Rare earth micronutrients-->fergusonite-->THULIUM-->YTTERBIUM-->LUTETIUM
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