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N-BENZYLQUININIUM CHLORIDE

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Products Intro: Product Name:N-BENZYLQUININIUM CHLORIDE
CAS:67174-25-8
Purity:99.99% Package:1g;1850USD
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CAS:67174-25-8
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CAS:67174-25-8
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CAS:67174-25-8
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Products Intro: Product Name:N-BENZYLQUININIUM CHLORIDE
CAS:67174-25-8
Purity:99.0% Package:1KG;0.1USD

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N-BENZYLQUININIUM CHLORIDE Basic information
Product Name:N-BENZYLQUININIUM CHLORIDE
Synonyms:N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst];N-BENZYLQUININIUM CHLORIDE;QUIBEC;N-Benzylquininium chloride ,98%;CinchonaniuM, 9-hydroxy-6'-Methoxy-1-(phenylMethyl)-,chloride, (8a,9R)-;1-Benzylquininium chloride;N-Benzylquininium chloride 95%;(2S,4S,5R)
CAS:67174-25-8
MF:C27H31ClN2O2
MW:451.01
EINECS:224-828-9
Product Categories:Ammonium Chlorides (Quaternary);Asymmetric Synthesis;Biochemistry;Chiral Phase-Transfer Catalysts;Quaternary Ammonium Compounds;Quinoline Alkaloids;Quinolines;Synthetic Organic Chemistry;Alkaloids;Alkoxyquinolines
Mol File:67174-25-8.mol
N-BENZYLQUININIUM CHLORIDE Structure
N-BENZYLQUININIUM CHLORIDE Chemical Properties
Melting point 200-205 °C (dec.) (lit.)
refractive index 227.5 ° (C=1.5, H2O)
storage temp. 2-8°C
form powder to crystal
color White to Light yellow
optical activity[α]20/D 235°, c = 1.5 in H2O
BRN 5702637
CAS DataBase Reference67174-25-8
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
N-BENZYLQUININIUM CHLORIDE Usage And Synthesis
Chemical PropertiesOff-white to brown powder
UsesN-Benzylquininium chloride can be used as a phase transfer catalyst:
  • In the sulfenylation of various β-keto sulfoxides.
  • To synthesize N-carbamoyl-protected β-nitroamines from α-amido sulfones by asymmetric aza-Henry reaction.

General DescriptionN-Benzylquininium chloride (or Quibec) belongs to the class of cinchona family of alkaloids. It is used as a catalyst in the presence of hydroxide bases in various phase transfer reactions, epoxidations, alkylations, and Michael reactions.
N-BENZYLQUININIUM CHLORIDE Preparation Products And Raw materials
Raw materialsBenzyl chloride-->Quinine
Tag:N-BENZYLQUININIUM CHLORIDE(67174-25-8) Related Product Information
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