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ZIRCONIUM N-PROPOXIDE

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CAS:23519-77-9
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ZIRCONIUM N-PROPOXIDE Basic information
Product Name:ZIRCONIUM N-PROPOXIDE
Synonyms:1-Propanol,zirconium(4+)salt;1-propanol,zirconium(4++)salt;Propylalcohol,zirconium(4+)salt;TETRA-N-PROPYL ZIRCONATE;TETRAPROPYL ZIRCONATE;N-PROPYL ZIRCONATE;Zirconium n-propoxide (23-28% free alcohol);zirconium tetrapropanolate
CAS:23519-77-9
MF:C12H28O4Zr
MW:327.57
EINECS:245-711-9
Product Categories:metal alkoxide
Mol File:23519-77-9.mol
ZIRCONIUM N-PROPOXIDE Structure
ZIRCONIUM N-PROPOXIDE Chemical Properties
Boiling point 208 °C0.1 mm Hg
density 1.058 g/mL at 20 °C
vapor pressure 19.4hPa at 20℃
refractive index n20/D 1.454
Fp 83 °F
solubility Alcohol,Toluene[soluble in]
form Slightly Viscous Solution
Specific Gravity1.05
color Colorless to yellow to light amber
Water Solubility Not miscible in water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 3679533
Exposure limitsACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
InChIKeyXPGAWFIWCWKDDL-UHFFFAOYSA-N
LogP0.34 at 20℃
CAS DataBase Reference23519-77-9(CAS DataBase Reference)
EPA Substance Registry System1-Propanol, zirconium(4+) salt (23519-77-9)
Safety Information
Hazard Codes Xi
Risk Statements 10-41-67
Safety Statements 26-39
RIDADR UN 1993 3/PG 3
WGK Germany 1
10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
ZIRCONIUM N-PROPOXIDE Usage And Synthesis
Chemical Propertiesslightly viscous colorless to pale yellow solution
UsesZirconium(IV) n-propoxide is used as a precursor in the production of zirconia. It is also used to study the thermophysical properties like thermal conductivity and thermal effusivity of hybrid films and thereby adjusting optic properties of the films.
General DescriptionA yellow-colored liquid with an alcohol-like odor. Has about the same density as water and is insoluble in water. Flash point below 141°F. Vapors are heavier than air. May be irritating to skin, eyes, and mucous membranes.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity ProfileOrganometallics, such as TETRA-N-PROPYL ZIRCONATE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
reaction suitabilitycore: zirconium
reagent type: catalyst
Purification MethodsAlthough it was reported that it could not be crystallised or sublimed even at 150o/10-4mm [Bradley & Wardlaw J Chem Soc 280 1951], the propoxide, when properly prepared, has been purifed by distillation in a high vacuum [Bradley et al. J Chem Soc 2025 1953]. [Beilstein 1 IV 1420.]
ZIRCONIUM N-PROPOXIDE Preparation Products And Raw materials
Tag:ZIRCONIUM N-PROPOXIDE(23519-77-9) Related Product Information
ZIRCONIUM N-BUTOXIDE ZIRCONIUM I-PROPOXIDE ISOPROPANOL ADDUCT,ZIRCONIUM I-PROPOXIDE 1-Propanol Butylmagnesium chloride n-Butyllithium Zirconium hydroxide Zirconium nitride Zirconium silicide Bis(cyclopentadienyl)zirconium chloride hydride Zirconium tetrachloride Zirconium oxide sulfate ZIRCONIUM(IV) ETHOXIDE LITHIUM ORTHOSILICATE Sodium orthovanadate ZIRCONIUM(IV) TERT-BUTOXIDE Zirconium hydroxide octanoic acid, zirconium salt ZIRCONIUM N-PROPOXIDE

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