α-ヘキシルシンナムアルデヒド(101-86-0)

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α-ヘキシルシンナムアルデヒド 製品概要
化学名:α-ヘキシルシンナムアルデヒド
英語化学名:alpha-Hexylcinnamaldehyde
别名:(2Z)-2-Hexyl-3-phenyl-2-propenal;.alpha.-hexylcinnamaldehyde(positivecontrolchemical);2-(phenylmethylene)-octana;2-(Phenylmethylene)octanal,a-Hexyl-phenylacrolein;A-N-HEXYL-B-PHENYLACROLEIN;ALPHA-HEXYLCINNAMIC ALDEHYDE;ALPHA-HEXYLCINNAMALDEHYDE;ALPHA-N-HEXYLCINNAMALDEHYDE
CAS番号:101-86-0
分子式:C15H20O
分子量:216.32
EINECS:202-983-3
カテゴリ情報:Aldehydes;C10 to C21;Carbonyl Compounds;aldehyde Flavor;Pharmaceutical Intermediates;Alphabetical Listings;Flavors and Fragrances;G-H;11
Mol File:101-86-0.mol
α-ヘキシルシンナムアルデヒド
α-ヘキシルシンナムアルデヒド 物理性質
沸点 174-176 °C/15 mmHg (lit.)
比重(密度) 0.95 g/mL at 25 °C (lit.)
FEMA 2569 | ALPHA-HEXYLCINNAMALDEHYDE
屈折率 n20/D 1.55(lit.)
闪点 200 °F
貯蔵温度 -20°C
溶解性water: soluble0.005g/L at 25°C
外見 Oil
Clear Yellow
臭い (Odor)at 100.00 %. fresh floral green jasmin herbal waxy
においのタイプfloral
JECFA Number686
安定性:Hygroscopic
LogP5.33
CAS データベース101-86-0(CAS DataBase Reference)
NISTの化学物質情報Octanal, 2-(phenylmethylene)-(101-86-0)
EPAの化学物質情報.alpha.-Hexylcinnamaldehyde (101-86-0)
安全性情報
主な危険性 C,Xi
Rフレーズ 36/37/38-34-43-52/53
Sフレーズ 26-36/37/39-45-36-36/37-61
RIDADR UN 3265 8/PG 3
WGK Germany 2
RTECS 番号GD6560000
HSコード 29122990
毒性The acute oral LD50 value in rats was reported as 3.1 g/kg (2.45-3.75 g/kg) (Moreno, 1971). The acute dermal LD50 value in rabbits was reported as > 3 g/kg (Moreno, 1971).
MSDS Information
ProviderLanguage
SigmaAldrich English
α-ヘキシルシンナムアルデヒド Usage And Synthesis
外観ごくうすい黄色〜黄色, 澄明の液体
定義本品は、次の化学式で表される環式アルデヒド化合物である。
溶解性水にほとんど溶けない。エタノール及びアセトンと混和する。
用途香料(ジャスミン,チュベローズなど花香の調合) (NITE CHRIP)
用途有機合成原料、香料材料。
化粧品の成分用途香料
説明α-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.
化学的特性alpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.
化学的特性Pale-yellow liquid; jasminelike odor, particularly on dilution. Soluble in most fixed oils and in mineral oil; insoluble in glycerol and in propylene glycol.
化学的特性Hexyl cinnamaldehyde has a jasmine-like odor, particularly on dilution.
天然物の起源Reported found in cooked, scented rice.
使用α-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.
使用hexyl cinnamal is also known as hexyl cinnamic aldehyde. It is a fragrance that provides a floral, jasmine-like scent.
定義ChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.
製造方法By condensation of octylaldehyde with benzaldehyde
Taste threshold valuesTaste characteristics at 5 ppm: sweet, waxy, floral, green, citrus and fruity nuances
一般的な説明Solubilization of α-hexylcinnamaldehyde by the ionic surfactants, sodium dodecyl sulfate and dodecyltrimethylammonium chloride and a non-ionic surfactant such as dodecyl polyoxyethylene ethers has been investigated.
危険性Combustible.
接触アレルゲンHexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.
Tags:101-86-0