α-アミルシンナムアルデヒド(122-40-7)

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α-アミルシンナムアルデヒド 製品概要
化学名:α-アミルシンナムアルデヒド
英語化学名:alpha-Amylcinnamaldehyde
别名:Heptanal,2-(phenylmethylene)-;Jasminaldehyde;Jasminealde-hyde;pentaamylcinnamicaldehyde;pentyl-3-phenyl-2-propenal;pentylcinnamaldehyde;Pentylcinnamicaldehyde;-Pentyl-pheny-lacrolein
CAS番号:122-40-7
分子式:C14H18O
分子量:202.29
EINECS:204-541-5
カテゴリ情報:A-B;Alphabetical Listings;Flavors and Fragrances;Aldehydes;C10 to C21;Carbonyl Compounds;Pharmaceutical Intermediates;11
Mol File:122-40-7.mol
α-アミルシンナムアルデヒド
α-アミルシンナムアルデヒド 物理性質
融点 80°C
沸点 287-290 °C(lit.)
比重(密度) 0.97 g/mL at 25 °C(lit.)
蒸気圧0.133Pa at 25℃
FEMA 2061 | ALPHA-AMYLCINNAMALDEHYDE
屈折率 n20/D 1.557(lit.)
闪点 >230 °F
貯蔵温度 2-8°C
溶解性Insoluble in water
Pale-yellow oil or liquid
臭い (Odor)floral jasmine odor
においのタイプfloral
水溶解度 181.69mg/L at 25℃
JECFA Number685
LogP2.498 at 25℃
CAS データベース122-40-7(CAS DataBase Reference)
NISTの化学物質情報Heptanal, 2-(phenylmethylene)-(122-40-7)
EPAの化学物質情報2-(Phenylmethylene)heptanal (122-40-7)
安全性情報
主な危険性 Xi,N
Rフレーズ 36/37/38-51/53-43
Sフレーズ 26-37/39-61-36/37
RIDADR UN 3082 9 / PGIII
WGK Germany 2
RTECS 番号GD6825000
国連危険物分類 9
容器等級 III
HSコード 29122990
有毒物質データの122-40-7(Hazardous Substances Data)
毒性LD50 orl-rat: 3730 mg/kg FCTXAV 2,327,64
MSDS Information
ProviderLanguage
Amylcinnamaldehyde English
SigmaAldrich English
α-アミルシンナムアルデヒド Usage And Synthesis
外観無色~黄色、澄明の液体
定義本品は、次の化学式で表される芳香族アルデヒドである。
溶解性エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。
解説

2-pentyl-3-phenyl-2-propen-1-ol.C14H18O(202.29).2-ベンジリデンヘプタナールともいう.ベンズアルデヒドとヘプタナールとをアルカリ溶液中で縮合させると得られる合成香料."淡黄色の液体.沸点147~175 ℃(2.6 kPa).d20200.9711.n20D1.5381.ジャスミン,スズラン,ライラックなどの花精油香料の調合用に広く用いられている.LD50 3730 mg/kg(ラット,経口).[CAS 122-40-7]
森北出版「化学辞典(第2版)

用途有機合成原料。
用途セッケン,洗剤などの調合香料
化粧品の成分用途香料
使用上の注意アルゴン封入
説明Amylcinnamic aldehyde is an oxidation product of amylcinnamic alcohol, one component of the "fragrance mix" and can be found as a sensitizer in cases of contact dermatitis in bakers.
化学的特性α-Amylcinnamaldehyde has a distinct floral (jasmine, lily) note.
化学的特性Light yellow transparent liquid
化学的特性alpha-Amylcinnamaldehyde has been identified as an aroma volatile of black tea. It is a light yellow liquid with a floral, slightly fatty odor, which becomes reminiscent of jasmine when diluted.The aldehyde is relatively unstable and must be stabilized by antioxidants.
It is prepared from benzaldehyde and heptanal in the same way as cinnamaldehyde.
??-Amylcinnamaldehyde is a very popular fragrance substance for creating jasmine notes. It is stable to alkali and long-lasting; large quantities are used, particularly in soap perfumes.
天然物の起源Reported found in black tea and soybean
使用amyl cinnamal is used as a fragrance. Although it is naturally occurring in some plants, it is most often synthetically derived when used in cosmetic products.
使用Raw material in the production of perfumes; some perfumery uses (tuberose; peach; cherry; Estee; honeysuckle Chevrefeuille) Cross: amylcinnamic alcohol. AMYL CINNAMAL
使用Amylcinnamaldehyde is a flavoring agent that is a yellow liquid with an odor similar to jasmine. It is insoluble in glycerin and propylene, soluble in fixed oils and mineral oil. It is obtained by chemical synthesis. It can be used alone or in combination with other flavoring substances or adjuvants. It is also termed amylcinnomaldehyde.
定義ChEBI: Alpha-Amylcinnamaldehyde is a member of cinnamaldehydes.
製造方法By condensation of n-amyl aldehyde with cinnamic aldehyde. This method of condensation of aromatic aldehydes with aliphatic aldehydes has the maximum yield in α-amylcinnamic aldehyde with little formation of the inferior homologs. The methyl, ethyl and propyl amylcinnamic aldehyde analogs exhibit a characteristic scent.
Taste threshold valuesTaste characteristics at 40 ppm: sweet, floral, spice-like with cinnamic and waxy nuance
一般的な説明The short-term feeding studies in rats was carried out using α-amylcinnamaldehyde, a flavouring matter.
燃焼性と爆発性Not classified
接触アレルゲンa-Amyl-cinnamic aldehyde is an oxidation product of amylcinnamic alcohol, a sensitizing fragrance, and one component of the “fragrance mix.” It can also be a sensitizer in bakers. It has to be mentioned by name in cosmetics within the EU.
安全性プロファイルModerately toxic by ingestion. A severe skin irritant. See also ALDEHYDES. When heated to decomposition it emits acrid smoke and irritating fumes.
代謝So far as is known, all aromatic aldehydes are metabolized in the animal body by oxidation to the corresponding acids. In some instances, the aldehydes are excreted as glucuronides. Cinnamic aldehyde is oxidized to cinnamic acid which is then degraded to benzoic acid, but ethyl cinnamic aldehyde is oxidized to the corresponding acid and is not further metabolized(Williams, 1959).
Tags:122-40-7