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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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Product Name:Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3] CAS:204933-84-6 Package:250mg;50mg
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Shanghai Incat Chemtech Co.,Ltd.
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021-57603038 13601791340 |
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Products Intro: |
Product Name:[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3] CAS:204933-84-6 Purity:97% Remarks:公斤级;100G;50G;10G
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| Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Basic information | Reaction |
Product Name: | Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) | Synonyms: | Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II) | CAS: | 204933-84-6 | MF: | 2C44H40P2.C2H7N.Cl.Cl3Ru2.ClH | MW: | 1686.99 | EINECS: | | Product Categories: | Ru | Mol File: | 204933-84-6.mol | |
| Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Chemical Properties |
Melting point | >100°C | storage temp. | 2-8°C | form | Powder | color | red-brown | Sensitive | air sensitive |
| Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Usage And Synthesis |
Reaction |
- Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
- The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
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| Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials |
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