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| | N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Basic information |
| Product Name: | N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE | | Synonyms: | 1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine;Allylbis(trimethylsilyl)amine;α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine;Einecs 231-699-2;N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE;N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine;2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&;N,N'-bis(trimethylsilyl)allylamine | | CAS: | 7688-51-9 | | MF: | C9H23NSi2 | | MW: | 201.46 | | EINECS: | 231-699-2 | | Product Categories: | Organometallic Reagents;Organosilicon;Others | | Mol File: | 7688-51-9.mol |  |
| | N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Chemical Properties |
| Boiling point | 72 °C/15 mmHg (lit.) | | density | 0.816 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.440(lit.) | | Fp | 109 °F | | form | liquid | | Specific Gravity | 0.817 | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| | N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Usage And Synthesis |
| Uses | N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
- Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
- Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
- Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive. |
| | N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE Preparation Products And Raw materials |
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