3-フェニルプロピオン酸メチル(103-25-3)

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3-フェニルプロピオン酸メチル 製品概要
化学名:3-フェニルプロピオン酸メチル
英語化学名:3-Phenylpropionic acid methyl ester
别名:methyl (3-phenyI) propanoate;Methyl 3-phenylpropanoate;Methyl benzenepropanoate;Methyl beta-phenylpropionate;Methyl dihydrocinnamate;Methyl esterof beta-Phenylpropionic acid;Methyl phenylpropionate;ASISCHEM D13382
CAS番号:103-25-3
分子式:C10H12O2
分子量:164.2
EINECS:203-092-2
カテゴリ情報:Pharmaceutical Intermediates;Aromatic Cinnamic Acids, Esters and Derivatives;Organic acids;103-25-3;11
Mol File:103-25-3.mol
3-フェニルプロピオン酸メチル
3-フェニルプロピオン酸メチル 物理性質
融点 142-145 °C
沸点 91-92 °C4 mm Hg(lit.)
比重(密度) 1.043 g/mL at 25 °C(lit.)
屈折率 n20/D 1.502(lit.)
FEMA 2741 | METHYL 3-PHENYLPROPIONATE
闪点 212 °F
貯蔵温度 Sealed in dry,Room Temperature
溶解性Chloroform (Slightly), Methanol (Slightly)
外見 Oil
Colourless to Pale Yellow
臭い (Odor)at 100.00 %. honey fruity wine balsam floral
においのタイプhoney
水溶解度 Soluble in chloroform. Insoluble in water.
JECFA Number643
BRN 1909591
InChIKeyRPUSRLKKXPQSGP-UHFFFAOYSA-N
LogP2.26
CAS データベース103-25-3(CAS DataBase Reference)
NISTの化学物質情報3-Phenylpropanoic acid methyl ester(103-25-3)
EPAの化学物質情報Benzenepropanoic acid, methyl ester (103-25-3)
安全性情報
Sフレーズ 24/25
WGK Germany 2
TSCA Yes
HSコード 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-フェニルプロピオン酸メチル Usage And Synthesis
外観無色~うすい黄色~うすい黄赤色透明液体
説明Methyl 3-phenylpropionate has a strong floral-fruity odor. May be prepared by reduction of methyl cinnamate in methanol solution with hydrogen and Ni under pressure.
化学的特性Clear light yellow liquid
化学的特性Methyl-3-phenylpropionate has a strong floral–fruity odor, with honey and wine-like undertones
天然物の起源Reported found in tabasco peppers, grapes, rhubarb, soursop and basil
使用Methyl 3-phenylpropionate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Phenylpropionic Acid Methyl Ester is an ester derivative of 3-phenylpropionic acid that is sometimes present in fragrance ingredients. It is also used as an application, aromatic intermediate.
製造方法By reduction of methyl cinnamate in methanol solution with hydrogen and Ni under pressure
定義ChEBI: Methyl 3-phenylpropanoate is a methyl ester resulting from the formal condensation of the carboxy group of 3-phenylpropionic acid with methanol. It has a role as a volatile oil component, a flavouring agent and a human metabolite. It is a methyl ester and a member of benzenes. It is functionally related to a 3-phenylpropionic acid.
Aroma threshold valuesAroma characteristics at 1.0%: sweet, rich spicy Ceylon cinnamonlike, balsamic with fruity, resinous and powdery nuances
Taste threshold valuesTaste characteristics at 5 ppm: cinnamon spicy, sweet, balsamic with fruity floral and resinous nuances.
Synthesis Reference(s)Tetrahedron Letters, 30, p. 5293, 1989 DOI: 10.1016/S0040-4039(01)93768-2
Journal of the American Chemical Society, 95, p. 625, 1973 DOI: 10.1021/ja00783a073
Tags:103-25-3