(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers list

Company Name:	Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel:	0371-65511006 18625597674
Email:	sales@kingorgchem.com

Company Name:	LaaJoo
Tel:	021-60702684 18516024827
Email:	huang.jiayi@sinocompound.com

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information

Product Name:	(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms:	(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(+)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine);(R)-iPr-MeOBIPHEP, SL-A116-1, (R)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl;SL-A116-1;(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%;(R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
CAS:	150971-45-2
MF:	C26H40O2P2
MW:	446.54
EINECS:
Product Categories:	Chiral Phosphine;MeOBIPHEP Series
Mol File:	150971-45-2.mol

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties

Boiling point	517.2±50.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	white
InChI	1S/C26H40O2P2/c1-17(2)29(18(3)4)23-15-11-13-21(27-9)25(23)26-22(28-10)14-12-16-24(26)30(19(5)6)20(7)8/h11-20H,1-10H3
InChIKey	HLLUWVKDDQIKNF-UHFFFAOYSA-N
SMILES	COc1cccc(P(C(C)C)C(C)C)c1-c2c(OC)cccc2P(C(C)C)C(C)C

Safety Information

MSDS Information

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis

Reactions	In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds. Conjugate addition using 2-heteroaryl titanates and zinc reagents. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran Rhodium-catalyzed carbonyl Z-dienylation. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
Chemical Properties	Off-white powder
Uses	Atropisomeric MeOBIPHEP ligands
General Description	sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Tag:(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(150971-45-2) Related Product Information

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl R(+)-2 2'-bis-(diphenylphosphino)-6 6'-& (S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (R)-DTBM-SEGPHOS (S)-H8-BINAP (R)-DM-BINAP (S)-SunPhos (S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-TolBINAP (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-SEGPHOS (R)-H8-BINAP (R)-DIFLUORPHOS(TM) (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS