1-オクテン-3-オール(3391-86-4)

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1-オクテン-3-オール 製品概要
化学名:1-オクテン-3-オール
英語化学名:1-Octen-3-ol
别名:1-Okten-3-ol;1-vinylhexanol;Flowtron mosquito attractant;matsutakealcohol;n-Oct-1-en-3-ol;Oct-1-ene-3-ol;octene-1-ol-3;Pentyl vintyl carbinol
CAS番号:3391-86-4
分子式:C8H16O
分子量:128.21
EINECS:222-226-0
カテゴリ情報:Flavors and Fragrances;alcohol Flavor;API intermediates
Mol File:3391-86-4.mol
1-オクテン-3-オール
1-オクテン-3-オール 物理性質
融点 -49°C
沸点 84-85 °C/25 mmHg (lit.)
比重(密度) 0.837 g/mL at 20 °C 0.83 g/mL at 25 °C (lit.)
蒸気圧1 hPa (20 °C)
FEMA 2805 | 1-OCTEN-3-OL
屈折率 n20/D 1.437(lit.)
闪点 142 °F
貯蔵温度 Inert atmosphere,Room Temperature
溶解性Acetonitrile (Slightly), Chloroform, Ethyl Acetate (Slightly)
酸解離定数(Pka)14.63±0.20(Predicted)
外見 Liquid
Clear colorless to pale yellow
比重0.84
臭い (Odor)at 10.00 % in dipropylene glycol. mushroom earthy green oily fungal raw chicken
においのタイプearthy
爆発限界(explosive limit)0.9-8%(V)
水溶解度 Not miscible or difficult to mix in water.
JECFA Number1152
BRN 1744110
InChIKeyVSMOENVRRABVKN-UHFFFAOYSA-N
LogP2.64
CAS データベース3391-86-4(CAS DataBase Reference)
NISTの化学物質情報1-Octen-3-ol(3391-86-4)
EPAの化学物質情報1-Octen-3-ol (3391-86-4)
安全性情報
主な危険性 Xn
Rフレーズ 22-36/38-20/21/22
Sフレーズ 26-36
RIDADR 2810
WGK Germany 3
RTECS 番号RH3300000
自然発火温度245 °C
TSCA Yes
国連危険物分類 6.1(b)
容器等級 III
HSコード 29052990
毒性LD50 orally in Rabbit: 340 mg/kg LD50 dermal Rabbit 3300 mg/kg
MSDS Information
ProviderLanguage
1-Octen-3-ol English
SigmaAldrich English
ACROS English
ALFA English
1-オクテン-3-オール Usage And Synthesis
外観無色~うすい黄色、液体
用途有機合成原料。
用途ミントあるいは野菜類のフレーバー用としてまたラベンダーなどフレグランス用香料
使用上の注意窒素封入
説明l-Octen-3-ol has a powerful, sweet, earthy odor with a strong, herbaceous note reminiscent of lavender-lavandin, rose, and hay. It has a sweet, herbaceous taste. May be prepared from magnesium amyl bromide and acrolein.
化学的特性1-Octen-3-ol may occur in the optically active form. It is found, for example, in lavender oil and is a steam-volatile component of mushrooms. l-Octen-3-ol is a liquid with an intense mushroom, forest–earthy odor that can be prepared by a Grignard reaction from vinylmagnesium bromide and hexanal. It is used in lavender compositions and in mushroom aromas.
化学的特性1-Octen-3-ol has a powerful, sweet, earthy odor with a strong, herbaceous note reminiscent of lavender–lavandin, rose and hay. It has a sweet, herbaceous taste.
天然物の起源Originally reported found in the mushroom Armillaria matsutake, a parasite growing on the radical hairs of Pinus densiflora in the forests of Japan; it has been isolated also in the essential oils of Mentha pulegium L., lavender and Mentha timjia. Also reported found in over 160 foods and beverages including banana, kumquat peel oil, berries, currants, guava, grapes, raisin, melon, pineapple, asparagus, potato, tomato, Mentha oils, thyme, wheat bread, cheeses, buttermilk, boiled egg, fish, cooked meats, hop oil, beer, cognac, rum, grape wines, cocoa, coffee, tea, pecans, plum, oats, soybean, olive, cloudberry, plums, beans, mushroom, marjoram, starfruit, sesame seed, fig, kelp, rice, beans, litchi, calamus, dill, licorice, pumpkin, buckwheat, sweet corn, corn tortilla, malt, rice, wort, krill, rosemary, Bourbon vanilla, mountain papaya, endive, lemon balm, shrimp, oyster, crab, clam, scallop, truffle, winter savory, anise hyssop and maté.
使用(±)-1-Octen-3-ol, is one of the volatiles responsible for mold`s odor. It can be used in combination with carbon dioxide to attract insects in order to kill them. In animal study, 1-Octen-3-ol has been shown to interfere with dopamine transport in the brain of fruit flies, so it might be an environmental agent involved in parkinsonism.
製造方法From magnesium amyl bromide and acrolein.
定義ChEBI: An alkenyl alcohol with a structure based on a C8 unbranched chain with the hydroxy group at C-2 and unsaturation at C-11C-2.
Aroma threshold valuesDetection: 14 ppb; recognition: 25 ppb
Taste threshold valuesTaste characteristics at 10 ppm: mushroom, earthy, fungal, green, oily, vegetative, umami sensation and savory-brothy.
一般的な説明1-Octen-3-ol occurs naturally in mushrooms. It is the most prominent odor volatile produced by fungi such as Aspergillus, Penicillium and Fusarium species. 1-Octen-3-ol is also formed in major quantity when soybeans are soaked in water as a pretreatment before soymilk production. It is also a potent mosquito attractant.
燃焼性と爆発性Not classified
製品名Matsutakeol (Takasago).
Biochem/physiol ActionsTaste at 0.01-0.20 ppm
安全性プロファイルPoison by ingestion and intravenous routes. Moderately toxic by skin contact. When heated to decomposition it emits acrid smoke and irritating fumes.
Tags:3391-86-4