alpha-Toluenesulfonyl chloride

alpha-Toluenesulfonyl chloride Suppliers list

Company Name:	Huai Hua Binfengchem Co., Ltd Gold
Tel:	0745-2866851 17711757908
Email:	3907837691@qq.com

Company Name:	Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel:	4006356688 18621169109
Email:	market03@meryer.com

Company Name:	TCI (Shanghai) Development Co., Ltd.
Tel:	021-67121386
Email:	Sales-CN@TCIchemicals.com

alpha-Toluenesulfonyl chloride manufacturers

alpha-Toluenesulfonyl chloride Basic information

Product Name:	alpha-Toluenesulfonyl chloride
Synonyms:	α-Toluenesulfonyl chloride ,98%;Benzylsulfonyl chlorideDISC 06/12/2000;Phenylmethanesulphonyl chloride;alpha-Toluenesulfonyl chloride, 98% 5GR;NSC 41894;Toluen-alphaSulfonyl chloride;ALPHA TOLUENE SULHONYL CHLORIDE;Benzenemethanesulfonylchloride
CAS:	1939-99-7
MF:	C7H7ClO2S
MW:	190.65
EINECS:	217-717-1
Product Categories:	Building Blocks;Chemical Synthesis;Pharmaceutical Intermediates;Organic Building Blocks;Sulfonyl Halides;Sulfur Compounds;Benzene derivatives;Benzenesulfonyl chloride
Mol File:	1939-99-7.mol

alpha-Toluenesulfonyl chloride Chemical Properties

Melting point	92-94 °C(lit.)
Boiling point	120 °C / 10mmHg
density	1.3264 (estimate)
refractive index	1.624-1.626
storage temp.	Inert atmosphere,2-8°C
solubility	soluble in Toluene
form	Crystalline Powder
color	Almost white
Water Solubility	decomposes
Sensitive	Moisture Sensitive
BRN	972806
InChI	1S/C7H7ClO2S/c8-11(9,10)6-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey	OAHKWDDSKCRNFE-UHFFFAOYSA-N
SMILES	ClS(=O)(=O)Cc1ccccc1
CAS DataBase Reference	1939-99-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanesulfonyl chloride(1939-99-7)
EPA Substance Registry System	Benzenemethanesulfonyl chloride (1939-99-7)

Safety Information

Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45
RIDADR	UN 3261 8/PG 2
WGK Germany	3
F	10-21
Hazard Note	Corrosive
TSCA	TSCA listed
HazardClass	8
PackingGroup	II
HS Code	29049020
Storage Class	8A - Combustible corrosive hazardous materials
Hazard Classifications	Skin Corr. 1B

MSDS Information

alpha-Toluenesulfonyl chloride Usage And Synthesis

Synthesis	Starting with benzaldehyde, a benzothiourea structure is generated through reduction, chlorination, and substitution reactions. Finally, alpha-Toluenesulfonyl chloride is obtained via sulfonyl chloride reaction.
Chemical Properties	almost white crystalline powder
Uses	a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction.
Synthesis Reference(s)	The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013 Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333
General Description	Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.

alpha-Toluenesulfonyl chloride Preparation Products And Raw materials

Raw materials	2,3-Dichloro-5,8-dihydroxy-1,4-naphthoquinone
Preparation Products	Bensulfuron methyl-->2-methoxycarbonylbenzylsulfonamide-->N-Methyl-1-(4-nitrophenyl)methanesulfonamide-->(4-Nitrophenyl)methanesulfonyl chloride-->Benzenemethanesulfonic acid, ethyl ester-->N,1-diphenylmethanesulfonamide

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