(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers list

Company Name:	XINXIANG RUNYU MATERIAL CO., LTD.
Tel:	+86-13592593621; +8613592593621
Email:	sales@runvmat.com
Products Intro:	Product Name:(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE CAS:148461-14-7 Purity:98%+ Package:1KG;\|10KG;\|25KG;

Company Name:	Shanghai Daken Advanced Materials Co.,Ltd
Tel:	+86-2158073036
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Products Intro:	Product Name:(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE CAS:148461-14-7 Purity:99% Package:1KG,5KG,10KG

Company Name:	career henan chemical co
Tel:	+86-0371-86658258 +8613203830695
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Products Intro:	Product Name:(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE CAS:148461-14-7 Purity:99% Package:3KG;3USD

Company Name:	SHANGHAI T&W PHARMACEUTICAL CO., LTD.
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Products Intro:	Product Name:(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline CAS:148461-14-7 Purity:99% HPLC Package:5KG;1KG

Company Name:	Dayang Chem (Hangzhou) Co.,Ltd.
Tel:	+86-0571-88938639 +8617705817739
Email:	info@dycnchem.com
Products Intro:	Product Name:(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline CAS:148461-14-7 Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:High quality

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE manufacturers

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Basic information

Product Name:	(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
Synonyms:	(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
CAS:	148461-14-7
MF:	C24H24NOP
MW:	373.43
EINECS:
Product Categories:	Chiral Phosphine;PHOX Series;organophosphine ligand
Mol File:	148461-14-7.mol

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties

Melting point	85-90 °C
Boiling point	492.7±28.0 °C(Predicted)
alpha	-44° (c 1.4, CHCl3)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
pka	4.31±0.70(Predicted)
color	white
Optical Rotation	[α]20/D 48±3°, c = 1% in chloroform
Sensitive	air sensitive
BRN	5879302
InChI	1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m1/s1
InChIKey	OUQSAXROROGQEE-JOCHJYFZSA-N
SMILES	CC(C)[C@H]1COC(=N1)c2ccccc2P(c3ccccc3)c4ccccc4

Safety Information

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Usage And Synthesis

Chemical Properties

White crystalline powder

Reactions

Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation.

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials

Tag:(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE(148461-14-7) Related Product Information

Phenyl phosphine Oxazoline (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE DIPHENYL(P-TOLYL)PHOSPHINE