DIBENZYL MALONATE manufacturers
- DIBENZYL MALONATE
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- $0.00 / 1kg
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2022-10-18
- CAS:15014-25-2
- Min. Order: 1kg
- Purity: 98%
- Supply Ability: 1Ton
- DIBENZYL MALONATE
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- $1.00 / 1KG
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2019-09-02
- CAS:15014-25-2
- Min. Order: 1KG
- Purity: 98%
- Supply Ability: 200kg
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| | DIBENZYL MALONATE Basic information |
| | DIBENZYL MALONATE Chemical Properties |
| Boiling point | 188 °C/0.2 mmHg (lit.) | | density | 1.137 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.546(lit.) | | Fp | >230 °F | | storage temp. | Sealed in dry,Room Temperature | | pka | 11.65±0.46(Predicted) | | form | clear liquid | | color | Colorless to Light yellow to Light orange | | Specific Gravity | 1.17 | | Water Solubility | Sparingly soluble in water; miscible in all proportions with ether and alcohol. | | BRN | 1998264 | | InChIKey | RYFCSKVXWRJEOB-UHFFFAOYSA-N | | CAS DataBase Reference | 15014-25-2(CAS DataBase Reference) |
| Safety Statements | 23-24/25 | | WGK Germany | 3 | | HS Code | 29171910 |
| | DIBENZYL MALONATE Usage And Synthesis |
| Chemical Properties | CLEAR YELLOWISH LIQUID | | Uses | Dibenzyl malonate was used in the preparation of tetraethyl 3,3-bis(benzyloxycarbonyl)propylene bisphosphonate. It was also used in the preparation of benzyl umbelliferone-3-carboxylate via Knoevenagel condensation with 2,4-dihydroxybezaldehyde. | | General Description | Direct asymmetric reaction of dibenzyl malonate with N-tert-butoxycarbonyl aldimines in the presence of Yb(OTf)3 and iPr-pybox (pybox = pyridine bisoxazoline) complexes has been investigated. | | Purification Methods | Dissolve the ester in toluene, wash it with aqueous NaHCO3, H2O, dry over MgSO4, filter, evaporate and distil it at high vacuum. [Ginsburg & Pappo J Am Chem Soc 75 1094 1953, Baker et al. J Org Chem 17 77 1952, Beilstein 6 IV 2270.] |
| | DIBENZYL MALONATE Preparation Products And Raw materials |
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