(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers list
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Products Intro: CAS:169689-05-8
Purity:98% Package:g-Kg
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Products Intro: Product Name:(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS:169689-05-8
Purity:99% Package:3KG;3USD
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Products Intro: Product Name:(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl)
CAS:169689-05-8
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Products Intro: Product Name:(S,S)-DACH-phenyl Trost Ligand
CAS:169689-05-8
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Products Intro: Product Name:1S,2S-DHAC-Phenyl Trost Ligand
CAS:169689-05-8
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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information
Reaction
Product Name:(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:(1S,2S)-(-)-1,2-TROST LIGAND;(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand;1S,2S- DHAC-Phenyl Trost Ligand;95% (S,S)-DACH-Phenyl Trost Ligand
CAS:169689-05-8
MF:C44H40N2O2P2
MW:690.76
EINECS:
Product Categories:Chiral Nitrogen;DACH&Trost Series
Mol File:169689-05-8.mol
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Structure
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties
Melting point 134-136°C
alpha -134o (C=1 IN METHANOL)
Boiling point 817.0±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
pka13.35±0.40(Predicted)
color white to off-white
Optical Rotation[α]20/D -134°, c = 1 in methanol
InChIKeyAXMSEDAJMGFTLR-UVMLCQSKNA-N
SMILESP(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1C(=O)N[C@H]1CCCC[C@@H]1NC(C1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1)=O |&1:22,27,r|
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis
ReactionThe palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 169689-05-8_1
Reactions of 169689-05-8_2
UsesTrost Ligands for Asymmetric Allylic Alkylation
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials
Tag:(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)(169689-05-8) Related Product Information
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 1,2-Diaminocyclohexane (1S,2S)-(+)-1,2-Diaminocyclohexane 2-Diphenylphosphinobenzaldehyde (+/-)-trans-1,2-Diaminocyclohexane (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) N-(2-AMINO-CYCLOHEXYL)-ACETAMIDE

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