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Postion:Product Catalog >Chemical Reagents>Organic reagents>Borane>(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

Price $1
Package 1KG
Min. Order: 1G
Supply Ability: 100KG
Update Time: 2019-07-06

Product Details

Product Name: (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole CAS No.: 112022-83-0
Min. Order: 1G Purity: 98%
Supply Ability: 100KG Release date: 2019/07/06

AD68

(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Basic information
Reactions
Product Name: (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
Synonyms: ALPHA,ALPHA-DIPHENYL-D-PROLINOL METHYLBORONIC ACID CYCL-AMIDE-ESTER;(R)-(+)-2-METHYL-CBS-OXAZABOROLIDINE;(R)-2-METHYL-CBS-OXAZABOROLIDINE;(R)-2-METHYL-CBS-OXAZABOROLIDINE MONOHYDRATE;(R)-1-METHYL,3,3-DIPHENYL-TETRAHYDRO-PYRROLO(1,2-C)(1,3,2)OXAZABOROLE;(R)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-1H,3H-PYRROLO[1,2-C][1,3,2]OXAZABOROLE;(R)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-PYRROLO-[1,2-C][1,3,2]OXAZABOROLE;(R)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE
CAS: 112022-83-0
MF: C18H20BNO
MW: 277.17
EINECS: -0
Product Categories: Asymmetric Synthesis;B (Classes of Boron Compounds);B-Bromocatecholborane, etc.;Synthetic Organic Chemistry;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Reduction;organic or inorganic borate
Mol File: 112022-83-0.mol
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Structure
 
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties
Melting point  85-95 °C(lit.)
Boiling point  111 °C
density  0.95 g/mL at 25 °C
refractive index  68 ° (C=1, MeOH)
Fp  40 °F
storage temp.  2-8°C
form  Liquid
color  Colorless to amber
Water Solubility  Not miscible or difficult to mix in water.
Sensitive  Air & Moisture Sensitive
BRN  9059874
InChIKey VMKAFJQFKBASMU-QGZVFWFLSA-N
CAS DataBase Reference 112022-83-0(CAS DataBase Reference)
 
Safety Information
Hazard Codes  F,Xn,Xi
Risk Statements  11-38-48/20-63-65-67-36/37-19-40
Safety Statements  36/37-62-33-29-16-2-26
RIDADR  UN 1294 3/PG 2
WGK Germany  3
10
HazardClass  3
PackingGroup  II
HS Code  29319090
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Usage And Synthesis
Reactions
  1. Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
  2. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
  3. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
  4. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS. 
Chemical Properties white to light yellow crystal powde
Uses suzuki reaction

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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  • Since: 2014-12-17
  • Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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