| Product Identification | Back to Contents | 【Product Name】
Methyl 3-aminocrotonate | 【Synonyms】
3-Aminocrotonic acid methyl ester
beta-Aminocrotonic acid methyl ester
Crotonic acid, 3-amino-, methyl ester
Methyl 3-amino-2-butenoate
Methyl 3-aminobut-2-enoate
Methyl beta-aminocrotonate | 【CAS】
14205-39-1 | 【Formula】
C5H9NO2 | 【Molecular Weight】
115.13 | 【EINECS】
238-056-5 | 【RTECS】
EM9092500 | 【RTECS Class】
Primary Irritant | 【Beilstein/Gmelin】
956592 | 【Beilstein Reference】
2-03-00-00414 |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
White crystalline powder. | 【Solubility in water】
Very soluble | 【Melting Point】
83 - 84 | 【Boiling Point】
194 | 【Vapor Pressure】
0.45 (25 C) | 【pKa/pKb】
7.74 (pKb) | 【Partition Coefficient】
-.14 | 【Heat Of Vaporization】
43.0 kJ/mol | 【Vapor Density】
4 |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
| Handling and Storage | Back to Contents | 【Storage】
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. |
| Hazards Identification | Back to Contents | 【Ingestion】
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. | 【Inhalation】
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | 【Skin】
Causes skin irritation. | 【Eyes】
Causes eye irritation. | 【EC Risk Phrase】
R 22 36 | 【EC Safety Phrase】
S 26 36/37/39 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Poison Class】
4 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
91 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
3 | 【Stability】
Stable at room temperature in closed containers under normal storage and handling conditions. | 【Incompatibilities】
Strong oxidizing agents. | 【Decomposition】
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
|
| Company Name: |
J & K SCIENTIFIC LTD. |
| Tel: |
010-82848833 400-666-7788 |
| Fax: |
86-10-82849933 |
| WebSite: |
http://www.jkchemical.com |
| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Fax: |
021-67582001/03/05 |
| WebSite: |
http://chemicals.thermofisher.cn |
|