Chemical Safety Data Sheet MSDS / SDS

4-(4-Methoxyphenyl)-2-butanone

Revision Date:2023-12-07Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: 4-(4-Methoxyphenyl)-2-butanone
  • CBnumber: CB7731013
  • CAS: 104-20-1
  • EINECS Number: 203-184-2
  • Synonyms: 4-(4-methoxyphenyl)butan-2-one,Anisylacetone

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company: Chemicalbook
  • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
  • Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

  • Signal wordNo signal word
Hazard statement(s)
none
Prevention
none
Response
none
Storage
none
Disposal
none

SECTION 3: Composition/information on ingredients

Substance

  • Product name: 4-(4-Methoxyphenyl)-2-butanone
  • Synonyms: 4-(4-methoxyphenyl)butan-2-one,Anisylacetone
  • CAS: 104-20-1
  • EC number: 203-184-2
  • MF: C11H14O2
  • MW: 178.23

SECTION 4: First aid measures

Description of first aid measures

If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

NFPA 704

0
1
0
HEALTH 0 Poses no health hazard, no precautions necessary and would offer no hazard beyond that of ordinary combustible materials
FIRE 1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
REACT 0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Avoid breathing vapours, mist or gas. For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits
Does not contain substances with occupational exposure limits.

Exposure controls

Appropriate engineering controls

General industrial hygiene practice.

Personal protective equipment
Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

  • Appearancelight yellow liquid, clear
  • OdourNo data available
  • Odour ThresholdNo data available
  • pHNo data available
  • Melting point/freezing pointMelting point/range: 8 °C - lit.
  • Initial boiling point and boiling range 152 - 153 °C at 20 hPa - lit.
  • Flash point>113,00 °C - closed cup
  • Evaporation rateNo data available
  • Flammability (solid, gas)No data available
  • Upper/lower flammability or explosive limitsNo data available
  • Vapour pressureNo data available
  • Vapour densityNo data available
  • Relative density1,046 g/cm3 at 25 °C
  • Water solubilityNo data available
  • Partition coefficient: n-octanol/waterNo data available
  • Autoignition temperatureNo data available
  • Decomposition temperatureNo data available
  • ViscosityNo data available
  • Explosive propertiesNo data available
  • Oxidizing propertiesNo data available

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - > 5.000 mg/kg
LD50 Dermal - Rabbit - > 5.000 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: EL9085500
toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Russell, 1973)

SECTION 12: Ecological information

Toxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

No data available

SECTION 13: Disposal considerations

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

SECTION 14: Transport information

SECTION 14: Transport information

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:

UN number

ADR/RID:IMDG:IATA:ADR/RID:IMDG:IATA:
IATA:

UN number

ADR/RID: 2585 IMDG: 2585 IATA: 2585
ADR/RID: 2742 IMDG: 2742 IATA: 2742
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3077 IMDG: 3077 IATA: 3077
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3 IMDG: 3 IATA: 3
ADR/RID: 3077 IMDG: 3077 IATA: 3077
ADR/RID: 2789 IMDG: 2789 IATA: 2789
ADR/RID: - IMDG: - IATA: -
ADR/RID: 2554 IMDG: 2554 IATA: 2554

UN proper shipping name

ADR/RID: METHYLALLYL CHLORIDE IMDG: METHYL ALLYL CHLORIDE IATA: Methylallyl chloride
ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods
ADR/RID: ACETIC ACID, GLACIAL IMDG: ACETIC ACID, GLACIAL IATA: Acetic acid, glacial
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (9,10-Dichloro- 1,2,3,4,5,6,7,8-octafluoroanthracene) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (9,10-Dichloro- IATA: Environmentally hazardous substance, solid, n.o.s. 1,2,3,4,5,6,7,8-octafluoroanthracene) (9,10-Dichloro-
ADR/RID: II IMDG: II IATA: II
ADR/RID: - IMDG: - IATA: -
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Amino-5- bromopyrimidine) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Amino-5- IATA: Environmentally hazardous substance, solid, n.o.s. bromopyrimidine)
ADR/RID: - IMDG: - IATA: -
ADR/RID: CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. (1-Chloroethyl chloroformate) IMDG: CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. (1-Chloroethyl chloroformate) IATA: Chloroformates, toxic, corrosive, flammable, n.o.s. chloroformate)
ADR/RID: ARYLSULPHONIC ACIDS, SOLID IMDG: ARYLSULPHONIC ACIDS, SOLID IATA: Arylsulphonic acids, solid

Transport hazard class(es)

ADR/RID: 8 IMDG: 8 IATA: 8
(1-Chloroethyl ADR/RID: 6.1 (3, 8) IMDG: 6.1 (3, 8) IATA: 6.1 (3)(8)
ADR/RID: no IMDG Marine pollutant: no IATA: no
(2-Amino-5- ADR/RID: 9 IMDG: 9 IATA: 9
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: 9 IMDG: 9 IATA: 9
ADR/RID: - IMDG: - IATA: -
ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3)
ADR/RID: - IMDG: - IATA: -
ADR/RID: 3 IMDG: 3 IATA: 3

Packaging group

ADR/RID: II IMDG: II IATA: II
ADR/RID: - IMDG: - IATA: -
ADR/RID: II IMDG: II IATA: II
ADR/RID: - IMDG: - IATA: -
ADR/RID: III IMDG: III IATA: III
No data available
ADR/RID: III IMDG: III IATA: III
No data available
ADR/RID: II IMDG: II IATA: II
ADR/RID: III IMDG: III IATA: III

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes bromopyrimidine) Special precautions for user Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes 1,2,3,4,5,6,7,8-octafluoroanthracene) Special precautions for user Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: no IMDG Marine pollutant: no IATA: no
ADR/RID: yes IMDG Marine pollutant: yes IATA: no

Special precautions for user

No data available
No data available
No data available
No data available
No data available
No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals
China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
Measures for Environmental Management of New Chemical Substances
United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/
EC Inventory:Listed.
Korea Existing Chemicals List (KECL):Not Listed. website: http://ncis.nier.go.kr
European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/
Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/
New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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