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ChemicalBook >> CAS DataBase List >> Allylboronic acid pinacol ester

Allylboronic acid pinacol ester

Allylboronic acid pinacol ester price.
  • $6 - $1566.18
  • Product name: Allylboronic acid pinacol ester
  • CAS: 72824-04-5
  • MF: C9H17BO2
  • MW: 168.04
  • EINECS:672-877-3
  • MDL Number:MFCD00013347
  • Synonyms:2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Allylboronic acid pinacol ester 97%;2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine);4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane;Allyl pinacol boronate;Pinacolyl 2-propenylboronate
47 prices
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  • Acrotein
  • AHH
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • AOBChem
  • Biosynth Carbosynth
  • Chemenu
  • Chem-Impex
  • ChemScene
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  • Matrix Scientific
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  • 100mg
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  • 100g
  • 250g
  • ManufacturerAcrotein
  • Product numberPB-0173
  • Product description(2-Propen-1-yl)-boronicacidpinacolester 97%
  • Packaging5g
  • Price$32.82
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-46851
  • Product descriptionAllylboronic acid pinacol ester 98%
  • Packaging25g
  • Price$380
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ91067
  • Product descriptionAllylboronic acid pinacol ester
  • Packaging1g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberB537
  • Product descriptionAllylboronic acid pinacol ester
  • Packaging25g
  • Price$101
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberB537
  • Product descriptionAllylboronic acid pinacol ester
  • Packaging4x25g
  • Price$327
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL16232
  • Product descriptionAllylboronic acid pinacol ester, 98+%
  • Packaging1g
  • Price$37.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL16232
  • Product descriptionAllylboronic acid pinacol ester, 98+%
  • Packaging5g
  • Price$148
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number72824045
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • Packaging50g
  • Price$268.66
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number72824045
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • Packaging250g
  • Price$799
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA115496
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine)
  • Packaging1g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA115496
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine)
  • Packaging5g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA115496
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine)
  • Packaging10g
  • Price$26
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA115496
  • Product description2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine)
  • Packaging25g
  • Price$57
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0002209
  • Product descriptionALLYLBORONIC ACID PINACOL ESTER 95.00%
  • Packaging1G
  • Price$613.31
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0002209
  • Product descriptionALLYLBORONIC ACID PINACOL ESTER 95.00%
  • Packaging5G
  • Price$881.27
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0002209
  • Product descriptionALLYLBORONIC ACID PINACOL ESTER 95.00%
  • Packaging25G
  • Price$1566.18
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein PB-0173 (2-Propen-1-yl)-boronicacidpinacolester 97% 5g $32.82 2021-12-16 Buy
AHH MT-46851 Allylboronic acid pinacol ester 98% 25g $380 2021-12-16 Buy
AK Scientific J91067 Allylboronic acid pinacol ester 1g $10 2021-12-16 Buy
AK Scientific B537 Allylboronic acid pinacol ester 25g $101 2021-12-16 Buy
AK Scientific B537 Allylboronic acid pinacol ester 4x25g $327 2021-12-16 Buy
Alfa Aesar L16232 Allylboronic acid pinacol ester, 98+% 1g $37.65 2024-03-01 Buy
Alfa Aesar L16232 Allylboronic acid pinacol ester, 98+% 5g $148 2024-03-01 Buy
Alichem 72824045 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 50g $268.66 2021-12-16 Buy
Alichem 72824045 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 250g $799 2021-12-16 Buy
Ambeed A115496 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine) 1g $6 2021-12-16 Buy
Ambeed A115496 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine) 5g $15 2021-12-16 Buy
Ambeed A115496 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine) 10g $26 2021-12-16 Buy
Ambeed A115496 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 97%(stabilizedwithPhenothiazine) 25g $57 2021-12-16 Buy
American Custom Chemicals Corporation BOR0002209 ALLYLBORONIC ACID PINACOL ESTER 95.00% 1G $613.31 2021-12-16 Buy
American Custom Chemicals Corporation BOR0002209 ALLYLBORONIC ACID PINACOL ESTER 95.00% 5G $881.27 2021-12-16 Buy
American Custom Chemicals Corporation BOR0002209 ALLYLBORONIC ACID PINACOL ESTER 95.00% 25G $1566.18 2021-12-16 Buy

Properties

Boiling point :50-53 °C/5 mmHg (lit.)
Density :0.896 g/mL at 25 °C (lit.)
refractive index :n20/D 1.4268(lit.)
Flash point :115 °F
storage temp. :2-8°C
solubility :Chloroform, Methanol (Slightly)
form :Liquid
color :Clear colorless
Water Solubility :Not miscible or difficult to mix in water.
BRN :4244068
CAS DataBase Reference :72824-04-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.

Description

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

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