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ChemicalBook CAS DataBase List NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY- PHTHALOCYANINE
155773-71-0

NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY- PHTHALOCYANINE synthesis

1synthesis methods
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Yield:155773-71-0 48%

Reaction Conditions:

in N,N-dimethyl-formamide;under Ar, a mixture of the organic ligand, Ni-salt and dimethylformamiderefluxed for 1.5 h and evaporated to dryness by rotary evaporation (45. degree.C); solid chromatographed twice (basic Al2O3 III, ethyl acetate-toluene, 1:2), further chromatographed (Bio-Beads S-X1, toluene), dissolved in CH2Cl2, recovered with CH3OH, washed with CH3OH, vacuum-dried (room temp.);

References:

Gunaratne, Tissa C.;Gusev, Alexey V.;Peng, Xinzhan;Rosa, Angela;Ricciardi, Giampaolo;Baerends, Evert Jan;Rizzoli, Corrado;Kenney, Malcolm E.;Rodgers, Michael A. J. [Journal of Physical Chemistry A,2005,vol. 109,# 10,p. 2078 - 2089]

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