ChemicalBook CAS DataBase List 2-Ethylhexyl nitrate

2-Ethylhexyl nitrate synthesis

3synthesis methods

Product Name:2-Ethylhexyl nitrate
CAS Number:27247-96-7
Molecular formula:C8H17NO3
Molecular Weight:175.23

104-76-7 Synthesis

104-76-7
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$5.00/10g

27247-96-7
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$72.00/1l

Yield:27247-96-7 100%

Reaction Conditions:

with sulfuric acid;nitric acid at 10; for 0.0333333 h;Large scale;

Steps:

2
[0029] A G4 Advanced-Flow reactor from Corning was configured and set up according to the description of Figure 4. A pump for 98% HN03 was set to l .OlKg/min (0.72L/min, 16mol/min), and a pump for 90% H2S04 was set to 3.03Kg/min (1.67L/min, 27.8mol/min), while a pump for alcohol was set to 2.08Kg/min (2.5L/min, 16mol/min), with a the chiller temperature set to 10° C. Samples were collected after the system stabilized (at about 2 minutes). GC analysis showed a full conversion of the starting material, and the yield was 100%. With total internal volume of 1.0L (4 modules), the retention time was (1.0L)/(4.89L/min)*60=12s (or liquid space velocity of 290h^_1).

References:

CORNING INCORPORATED;MA, Bing;SHEN, Wei;WANG, Yanhua;ZHANG, Mo WO2015/134703, 2015, A1 Location in patent:Paragraph 0029

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