3-(3,4-DIFLUOROPHENYL)-1-PROPENE synthesis
- Product Name:3-(3,4-DIFLUOROPHENYL)-1-PROPENE
- CAS Number:842124-23-6
- Molecular formula:C9H8F2
- Molecular Weight:154.16
591-87-7
196 suppliers
$10.00/10g
348-61-8
398 suppliers
$6.00/5g
842124-23-6
19 suppliers
$252.00/1g
Yield:842124-23-6 75%
Reaction Conditions:
Stage #1: 1-bromo-3,4-difluorobenzenewith magnesium;lithium chloride in tetrahydrofuran at 20; for 2 h;Inert atmosphere;
Stage #2: with iron(III)-acetylacetonate in tetrahydrofuran at 0; for 0.0833333 h;Inert atmosphere;
Stage #3: Allyl acetate in tetrahydrofuran at 0; for 0.75 h;Inert atmosphere;
References:
Mayer, Matthias;Czaplik, Waldemar M.;Von Wangelin, Axel Jacobi [Advanced Synthesis and Catalysis,2010,vol. 352,# 13,p. 2147 - 2152] Location in patent:supporting information; experimental part