3-Furancarboxylicacid,5-methyl-,methylester(9CI) synthesis
- Product Name:3-Furancarboxylicacid,5-methyl-,methylester(9CI)
- CAS Number:35351-35-0
- Molecular formula:C7H8O3
- Molecular Weight:140.14
123-38-6
292638-85-8
35351-35-0
Palladium(II) acetate [Pd(OAc)2] (0.2 mmol), H4PMo11V1O40 (15 μmol), cerium chloride heptahydrate (CeCl3-7H2O) (0.2 mmol), methanol (30 mmol), and acetic acid (4.5 mL) were added sequentially to the reactor. The reaction mixture was heated to 70 °C. A mixture of methyl acrylate (1 mmol), propionaldehyde (6 mmol) and acetic acid (0.5 mL) was added dropwise to the reaction system using a syringe pump at a rate of 5 μL/min under an oxygen atmosphere of 1 atm (0.1 MPa) for 8 hours. Upon completion of the reaction, the reaction mixture was analyzed by gas chromatography and the yield of methyl 5-methyl-3-furancarboxylate was measured to be 90%.
7424-91-1
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123-38-6
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35351-35-0
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Yield:35351-35-0 99 % Chromat.
Reaction Conditions:
with oxygen;acetic acid;palladium diacetate;cerium(III) chloride in methanol at 80; under 760.051 Torr; for 4.5 h;
References:
Tamaso, Ken-Ichi;Hatamoto, Yuji;Obora, Yasushi;Sakaguchi, Satoshi;Ishii, Yasutaka [Journal of Organic Chemistry,2007,vol. 72,# 23,p. 8820 - 8823]
123-38-6
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35351-35-0
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87241-03-0
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35351-35-0
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$45.00/10mg