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ChemicalBook CAS DataBase List 4-08-00-02739 (Beilstein Handbook Reference)
18256-48-9

4-08-00-02739 (Beilstein Handbook Reference) synthesis

9synthesis methods
Preparation by total hydrolysis of 3-methoxy4,a-diacetoxy-acetophenone (m.p. 77–78°) in methanol with concentrated hydrochloric acid,
for 4–5 h at r.t. (78%)
during 14 h at 20°, then for 30 min at reflux (67%).
-

Yield:18256-48-9 51%

Reaction Conditions:

with potassium phosphate buffer;thiamine diphosphate;magnesium sulfate;benzaldehyde lyase from Pseudomonas fluorescens in dimethyl sulfoxide at 37; pH=7.0;Enzymatic reaction;

References:

Demir, Ayhan S.;Ayhan, Peruze;Igdir, A. Cigdem;Duygu, A. Nese [Tetrahedron,2004,vol. 60,# 31,p. 6509 - 6512]