Benzene, 1-nitro-4-(2-phenylethoxy)- synthesis
- Product Name:Benzene, 1-nitro-4-(2-phenylethoxy)-
- CAS Number:92200-02-7
- Molecular formula:C14H13NO3
- Molecular Weight:243.26
Yield:92200-02-7 79%
Reaction Conditions:
with di-tert-butyl peroxide;1,3-di-tert-butylimidazolium at 130; for 24 h;Green chemistry;
Steps:
13 Example 13: [(tBuNCH=CHNtBu)CH][FeBr4]-catalyzed oxidative coupling reaction of 4-nitrophenol and ethylbenzene
Add 4-nitrophenol to the reaction flask one by one(69.5 mg, 0.5 mmol), catalyst (28 mg, 0.05 mmol),Di-tert-butyl peroxide (140 μl, 0.75 mmol),Toluene (4.5ml),React at 130 oC for 24 hours, cool to room temperature after the reaction, and purify the product by column chromatography.(Use a mixed solvent with a volume ratio of ethyl acetate/petroleum ether of 1:50 as the developing agent),The yield was 79%.
References:
CN112645821,2021,A Location in patent:Paragraph 0037; 0041
