BIS(4-NITROPHENYL) SULFIDE synthesis
- Product Name:BIS(4-NITROPHENYL) SULFIDE
- CAS Number:1223-31-0
- Molecular formula:C12H8N2O4S
- Molecular Weight:276.27
100-00-5
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$14.00/25g
1223-31-0
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$20.00/1g
Yield:1223-31-0 98%
Reaction Conditions:
with disodium sulphide at 120; for 12 h;Inert atmosphere;
Steps:
1
Under the protection of the nitrogen atmosphere, the 1-chloro-4-nitrobenzene (157 mg, 1mmol), sodium sulfide (39 mg, 0 . 5mmol), N, N-dicarboximide (2 ml) is added to the dry reaction tubes, at 120 °C reaction in oil bath 12h. After cooling the reaction system, by adding 15 ml of water, the aqueous phase with ethyl acetate 30 ml extraction 3 time, combined with the phase, solvent evaporation to dryness under reduced pressure, column chromatography on the obtained yellow solid, in other words, a second-(4-nitrophenyl) thio-ether (132 mg, yield is 98%).
References:
CN105218418,2016,A Location in patent:Paragraph 0045; 0046
350-46-9
525 suppliers
$10.60/1gm:
1223-31-0
86 suppliers
$20.00/1g
830-03-5
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$10.00/5g
1223-31-0
86 suppliers
$20.00/1g