CINNAMONITRILE synthesis
- Product Name:CINNAMONITRILE
- CAS Number:4360-47-8
- Molecular formula:C9H7N
- Molecular Weight:129.16
621-82-9
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4360-47-8
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Yield: 89%
Reaction Conditions:
with ammonium hydroxide;oxygen in tert-Amyl alcohol under 3750.38 Torr; for 18 h;Green chemistry;
Steps:
13 3-Phenylacryl alcohol was converted to 3-phenylacrylonitrile
Followed by meso-Co-N / C (800) (35 mg, 0.5 mol% Co)3-phenylpropene alcohol (67 mg,0.5 mL), 28% aqueous ammonia (140 [mu] L) was added to a 10 ml reaction flask and then added1ml tert-amyl alcohol as solvent, placed in the reactor, oxygen to 0.5Mpa, placed in 130 oil bath,The degree of reaction was then measured by GC-MS. After the reaction, the internal standard biphenyl was added and analyzed by GC Product 3-phenylacrylonitrile yield. Reaction 18h, 3-phenylacrylonitrile yield of 89%, selectivity of 97%.
References:
Dalian Institute of Chemical Physics;Gao Shuang;Shang Sensen;Wang Lianyue;Lv Ying CN106883143, 2017, A Location in patent:Paragraph 0058-0060
104-55-2
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621-79-4
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104-54-1
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107-13-1
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108-90-7
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4360-47-8
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