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Cinnamyl alcohol

Description References
Cinnamyl alcohol
Cinnamyl alcohol
CAS No.
104-54-1
Chemical Name:
Cinnamyl alcohol
Synonyms
Peruvin;Sterone;stylone;3-Phenyl;NSC 8775;FEMA 2294;NSC 623440;Ciamyl alcohol;trans-CinnaMyl;Styrylicalcohol
CBNumber:
CB5771763
Molecular Formula:
C9H10O
Formula Weight:
134.18
MOL File:
104-54-1.mol

Cinnamyl alcohol Properties

Melting point:
30-33 °C(lit.)
Boiling point:
250 °C(lit.)
Density 
1.044 g/mL at 25 °C(lit.)
vapor density 
4.6 (vs air)
vapor pressure 
<0.01 mm Hg ( 25 °C)
refractive index 
1.5819
FEMA 
2294 | CINNAMYL ALCOHOL
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
H2O: soluble
form 
Fused Low Melting Crystalline Solid
color 
White
Water Solubility 
1.8 g/L (20 ºC)
Merck 
14,2302
BRN 
1903999
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
104-54-1(CAS DataBase Reference)
NIST Chemistry Reference
2-Propen-1-ol, 3-phenyl-(104-54-1)
EPA Substance Registry System
2-Propen-1-ol, 3-phenyl-(104-54-1)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn
Risk Statements  22-36/38-43-36
Safety Statements  26-36/37-37/39-24-24/25
RIDADR  2811
WGK Germany  2
RTECS  GE2200000
10-23
TSCA  Yes
Hazardous Substances Data 104-54-1(Hazardous Substances Data)
Toxicity LD50 (g/kg): 2.0 orally in rats; >5.0 dermally in rabbits (Letizia)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Cinnamyl alcohol price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 108197 Cinnamyl alcohol 98% 104-54-1 100g $20.6 2018-11-13 Buy
Sigma-Aldrich 108197 Cinnamyl alcohol 98% 104-54-1 5g $21.7 2018-11-13 Buy
Alfa Aesar A13025 Cinnamyl alcohol, 98% 104-54-1 1000g $94 2018-11-13 Buy
Alfa Aesar A13025 Cinnamyl alcohol, 98% 104-54-1 250g $28.5 2018-11-13 Buy
Sigma-Aldrich W229411 Cinnamyl alcohol natural, 96%, FG 104-54-1 sample-k $40 2018-11-13 Buy

Cinnamyl alcohol Chemical Properties,Uses,Production

Description

As an organic compound, Cinnamic alcohol has a very distinct sweet, spicy, hyacinth odour that is found in resins, balsams and cinnamon leaves. It is used commonly in the fragrance industry due to its distinctive odour, which can be applied as a deodorant, fragrance and additive in cosmetic products and in the formulation of bath products, body and hand products, such as soaps, toothpaste, deodorants, etc. Besides, it also finds application as a food additive in chewing gum, bakery products, candy and soft drinks. Naturally, Cinnamyl alcohol is occurrent only in small amount, thus its industrial demand is usually fulfilled by chemical synthesis starting from the reduction of cinnamaldehyde.
Cinnamyl alcohol has been found to have a sensitising effect on some particular people, thus it is also considered as a Standardized Chemical Allergen. The physiologic effect of cinnamyl alcohol is caused by the Increased Histamine Release and cell-mediated Immunity.

References

https://en.wikipedia.org/wiki/Cinnamyl_alcohol
http://www.huidziekten.nl/allergie/stoffen/cinnamic-alcohol.htm
https://www.ulprospector.com/en/na/Food/Detail/13286/411638/Cinnamic-Alcohol
http://www.cosmeticsinfo.org/ingredient/cinnamyl-alcohol-0
https://pubchem.ncbi.nlm.nih.gov/compound/cinnamyl_alcohol#section=Top
http://www.somaiya.com/products/chemicals-pipeline/cinnamic-alcohol-1

Chemical Properties

colourless solid

Uses

Cinnamyl alcohol was used to study the alkylation of 2,4-di-tert-butylphenol by cinnamyl alcohol using aluminum-containing mesoporous ethane-silica catalyst. It was used to study gold nanoparticles supported on titanium dioxide catalysed oxidative coupling of alcohols and amines to form the corresponding imines.

Uses

In perfumery; as deodorant in 12.5% solution in glycerol.

Definition

ChEBI: A primary alcohol comprising an allyl core with a hydroxy substituent at the 1-position and a phenyl substituent at the 3-position (geometry of the C2C bond unspecified).

Contact allergens

Cinnamyl alcohol occurs (in esterified form) in storax, Myroxylon pereirae, cinnamon leaves, and hyacinth oil. It is obtained by the alkaline hydrolysis of storax and prepared synthetically by reducing cinnamal diacetate with iron filings and acetic acid, and from cinnamaldehyde by Meerwein-Ponndorf reduction with aluminum isopropoxide. Cinnamic alcohol is contained in the “fragrance mix.” As a fragrance allergen, it has to be mentioned by name in cosmetics within the EU. Occupational cases of contact dermatitis were reported in perfume industry. Patch tests can be positive in food handlers.

Purification Methods

Crystallise the alcohol from diethyl ether/pentane. [Beilstein 6 I 281.]

Cinnamyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products


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