N-TERT-BUTYLCYCLOHEXYLAMINE synthesis
- Product Name:N-TERT-BUTYLCYCLOHEXYLAMINE
- CAS Number:51609-06-4
- Molecular formula:C10H21N
- Molecular Weight:155.28
98-95-3
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75-65-0
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51609-06-4
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$65.00/100mg
108-91-8
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Yield:-
Reaction Conditions:
with hydrogen in water at 150; under 22502.3 Torr; for 10 h;Molecular sieve;Autoclave;chemoselective reaction;
Steps:
2.6. Catalytic one-pot multi-directional selective hydrogenation and Nalkylation
General procedure: In a typical procedure, 1 mmol nitrobenzene, 40 mg 5 wt%Ru/LDH,0.5 g 4 ? MS, and 5 mL isopropanol were added into the 60 mL highpressure reactor equipped with a pressure gauge, a magnetic stirrer,and an electric temperature controller. The reactor was purged fourtimes with hydrogen to remove the residual atmosphere, followed byfilling with 0.5 MPa H2, and then heated to a definite temperature for aperiod of time. After the reactor was cooled to 25 °C, the reactionmixture was separated by centrifugation. After the experiment, thecatalyst was filtered, washed three times with isopropanol and driedovernight in a 60 °C vacuum drying box. Recycle experiments werecarried out with the recovered catalyst. The resulting solution wasanalyzed on Agilent 7820A gas chromatograph equipped with a flameionization detector. The identification of the obtained products wascarried on an Agilent 7890B-5975 MSD-GC Mass spectrometerequipped with HP-5 column along with compared with known compounds.
References:
Zhang, Sishi;Xu, Jie;Cheng, Hongmei;Zang, Cuicui;Sun, Bin;Jiang, Heyan;Bian, Fengxia [Applied Catalysis A: General,2020,vol. 596,art. no. 117536] Location in patent:supporting information
75-64-9
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108-93-0
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51609-06-4
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$65.00/100mg
90977-47-2
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51609-06-4
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37810-16-5
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51609-06-4
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$65.00/100mg
108-94-1
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$12.00/50g
51609-06-4
24 suppliers
$65.00/100mg