(R)-2-HYDROXYMETHYL-PENTANOIC ACID synthesis
- Product Name:(R)-2-HYDROXYMETHYL-PENTANOIC ACID
- CAS Number:875125-87-4
- Molecular formula:C6H12O3
- Molecular Weight:132.16
Yield:875125-87-4 38%
Reaction Conditions:
Stage #1: formaldehyd;2-amino-hexanoic acidwith ketopantoate hydroxymethyltransferase I212A;cobalt(II) chloride at 20; pH=7.5; for 24 h;Enzymatic reaction;
Stage #2: with dihydrogen peroxide pH=7.5;
Stage #3: with catalase from bovine liver in aq. phosphate buffer; pH=7;Enzymatic reaction;enantioselective reaction;
References:
Pickl, Mathias;Marín-Valls, Roser;Joglar, Jesús;Bujons, Jordi;Clapés, Pere [Advanced Synthesis and Catalysis,2021,vol. 363,# 11,p. 2866 - 2876]
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