| Identification | More | [Name]
Dithiaanthraquinone-2,3-dinitrile | [CAS]
3347-22-6 | [Synonyms]
2，3-Dicyano-1，4-dithia-anthraquinone
2,3-DICYANO-1,4-DITHIAANTRAQUINONE
5,10-DIHYDRO-5,10-DIOXONAPHTHO-[2,3-B]-1,4-DITHIIN-2,3-DICARBONITRILE
5,10-DIHYDRO-5,10-DIOXONAPHTHO[2,3-B]-P-DITHIIN-2,3-DICARBONITRILE
5,10-DIOXO-5,10-DIHYDRO-NAPHTHO[2,3-B][1,4]DITHIINE-2,3-DICARBONITRILE
AKOS NCG1-0094
AKTUAN
CLUSTER
DELAN
DELAN-COL
DELAN(R)
Dicyano-1,4-dithia-anthraquinone
dithiaanthraquinone-2,3-dinitrile
DITHIANON
1,4-dithiaanthraquinone-2,3-dicarbonitrile
1,4-dithiaanthraquinone-2,3-dinitrile
2,3-dicarbonitrilo-1,4-diathiaanthrachinon
2,3-dinitrilo-1,4-dithia-9,10-anthraquinone
2,3-dinitrilo-1,4-dithiaanthraquinone
2,3-dinitrilo-1,4-dithia-anthraquinone | [EINECS(EC#)]
222-098-6 | [Molecular Formula]
C14H4N2O2S2 | [MDL Number]
MFCD00055492 | [Molecular Weight]
296.32 | [MOL File]
3347-22-6.mol |
| Chemical Properties | Back Directory | [Melting point ]
225° | [Boiling point ]
402.1±45.0 °C(Predicted) | [density ]
d18 1.55 | [refractive index ]
1.6360 (estimate) | [storage temp. ]
0-6°C | [form ]
neat | [Water Solubility ]
0.5mg/L(temperature not stated) | [Merck ]
13,3404 | [BRN ]
1325563 | [Contact allergens]
Dithianone is an anthraquinone derivative, used as a fungicide
agent. With cymoxanil, it is contained in Aktuan®.
Cases in agricultural workers were reported sparsely | [LogP]
2.840 | [CAS DataBase Reference]
3347-22-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Dithianone(3347-22-6) | [EPA Substance Registry System]
3347-22-6(EPA Substance) |
| Hazard Information | Back Directory | [Definition]
ChEBI: A naphthodithiin that is 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin which is substituted by nitrile groups at positions 2 and 3. It is a broad spectrum fungicide used to control scab, downy mildew, rust, and leaf spot in the commercial
rowing of grapes and other fruit, citrus, coffee, and vegetables. | [Uses]
Fungicide. | [Description]
Dithianone is an anthraquinone derivative, used as a
fungicide. With cymoxanil, it is contained in Aktuan.
Cases have been sparsely reported for agricultural
workers.
| [History]
The
ethylenebisdithiocarbamates were rediscovered in 1945
when Dimond et al. (2) reported a “new water soluble
protectant fungicide.” The parent compound, disodium
ethylenebisdithiocarbamate, was highly soluble in water
and was unstable in air, and it might have been only
a laboratory curiosity and remained unnoticed but for
the applications developed by Heuberger and Manns (3),
who stabilized it by converting it into zinc salt by the
addition of zinc sulfate–lime mixture. This was followed
by the introduction of zineb as fungicide by the Rohm and
Haas Company, USA.
The same phenomenon was later
confirmed by Barratt and Horsfall (4), who attributed
the stabilizing effect as due to zinc salt formation.
From the numerous compounds suggested by Hester (5),
only disodium ethylenebisdithiocarbamate and its zinc
and manganese salts are largely accepted for practical
application. Research on these dithiocarbamates led to
some promising variants. | [Agricultural Uses]
Fungicide: Fungicide used to control certain mildews. A seed
dressing; used to attack foliar diseases of fruits (pome,
stone, etc,), coffeee, wine, and vegetables. Not currently
registered for use in the U.S. Approved for use in most EU
countries.
| [Trade name]
DELAN®; DELAN-COL®; DELAN
70WG®; DITHIANON FLOWABLE®; DITHIANONWG®;
IT 931®; MV 119A®; STAUFFER MV-119A®;
THYNON® |
| Safety Data | Back Directory | [Hazard Codes ]
Xn;N,N,Xn | [Risk Statements ]
R22:Harmful if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S24:Avoid contact with skin .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 | [WGK Germany ]
3 | [RTECS ]
QL0700000 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29349990 | [Hazardous Substances Data]
3347-22-6(Hazardous Substances Data) | [Toxicity]
LD50 orally in rats, guinea pigs: 638, 110 mg/kg (Amadori, Heupt) |
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