| Identification | More | [Name]
Methyl 4-aminobenzoate | [CAS]
619-45-4 | [Synonyms]
4-AMINOBENZOIC ACID METHYL ESTER
4-AMINO METHYL BENZOATE
LABOTEST-BB LTBB000528
METHY-4-AMINO-BENZOIC ACID
METHYL 4-AMINOBENZOATE
METHYL P-AMINOBENZOATE
TIMTEC-BB SBB004063
4-(carbomethoxyl)aniline
4-(Methoxycarbonyl)aniline
4-amino-benzoicacimethylester
4-carbomethoxyaniline
Benzoic acid, p-amino-, methyl ester
benzoicacid,4-amino-,methylester
Methyl aniline-4-carboxylate
Methyl ester of 4-aminobenzoic acid
Methyl ester of p-Aminobenzoic acid
methylaniline-4-carboxylate
p-(Methoxycarbonyl)aniline
p-Aminobenzoic acid methyl ester
p-aminobenzoicacidmethylester | [EINECS(EC#)]
210-598-7 | [Molecular Formula]
C8H9NO2 | [MDL Number]
MFCD00007891 | [Molecular Weight]
151.16 | [MOL File]
619-45-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to beige crystals or crystalline powder | [Melting point ]
110-111 °C (lit.) | [Boiling point ]
273.17°C (rough estimate) | [density ]
1.2023 (rough estimate) | [refractive index ]
1.5810 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
3.82g/l | [form ]
Crystals or Crystalline Powder | [pka]
pK1:2.38(＋1) (25°C) | [color ]
White to beige | [Water Solubility ]
Soluble in alcohol and ether. Slightly soluble in water. | [BRN ]
775913 | [InChIKey]
LZXXNPOYQCLXRS-UHFFFAOYSA-N | [LogP]
1.370 | [CAS DataBase Reference]
619-45-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzoic acid, 4-amino-, methyl ester(619-45-4) | [EPA Substance Registry System]
619-45-4(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
DG2900000
| [TSCA ]
Yes | [HS Code ]
29224995 |
| Hazard Information | Back Directory | [Chemical Properties]
white to beige crystals or crystalline powder | [Uses]
Methyl 4-aminobenzoate is used in the synthesis of guanidine alkaloids, (±)-martinelline and (±)-martinellic acid by a protic acid catalyzed hetero Diels-Alder coupling reaction with N-Cbz 2-pyrroline. It is also used in organic synthesis and acts as a dye intermediate. Further, it is used to prepare 4-(2-methyl-4-oxo-4H-quinazolin-3-yl)-benzoic acid methyl ester by reacting with 2-acetylamino-benzoic acid. | [Synthesis Reference(s)]
Synthetic Communications, 26, p. 973, 1996 DOI: 10.1080/00397919608003701
Synthesis, p. 23, 1978 | [General Description]
The catalytic oxidation of methyl 4-aminobenzoate by hydrogen peroxide was studied. |
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