Hafniumcarbid

HAFNIUM CARBIDE Struktur
12069-85-1
CAS-Nr.
12069-85-1
Bezeichnung:
Hafniumcarbid
Englisch Name:
HAFNIUM CARBIDE
Synonyma:
HAFNIUM CARBIDE;hafnium,methane;hafnium(iv) carbide;Hafnium monocarbide;Hafnium carbide HfC;Hafnium carbide/ 99+%;Hafnium carbide ceramics;Hafnium Carbide, -325 Mesh;Methanidylidynehafnium(1+);Hafnium(IV) carbide, 99.8%
CBNumber:
CB0124513
Summenformel:
CHf
Molgewicht:
190.5
MOL-Datei:
12069-85-1.mol

Hafniumcarbid Eigenschaften

Schmelzpunkt:
2930 °C(lit.)
Dichte
12.2 g/mL at 25 °C(lit.)
RTECS-Nr.
MG4620000
Aggregatzustand
Powder
Farbe
Gray
Widerstand (resistivity)
45.0 (ρ/μΩ.cm)
Wasserlöslichkeit
it is insoluble in water.
Crystal Structure
Cubic, NaCl Structure
Expositionsgrenzwerte
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
InChIKey
NVDNLVYQHRUYJA-UHFFFAOYSA-N
CAS Datenbank
12069-85-1
EPA chemische Informationen
Hafnium carbide (HfC) (12069-85-1)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
RIDADR  UN3178
WGK Germany  3
TSCA  Yes
HazardClass  4.1
PackingGroup  III
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H228 Entzündbarer Feststoff. Entzündbare Feststoffe Kategorie 1 Achtung
Warnung
GHS hazard pictogramssrc="/GHS02.jpg" width="20" height="20" /> P210, P240,P241, P280, P370+P378
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P240 Behälter und zu befüllende Anlage erden.
P241 Explosionsgeschützte [elektrische/Lüftungs-/ Beleuchtungs-/...] Geräte verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P370+P378 Bei Brand: zum Löschen verwenden.

Hafniumcarbid Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

dark, gray, brittle solid; fcc, a=0.4640 nm; high cross section for absorption of thermal neutrons; resistivity 8.8μohm· cm; most refractory binary material known; hardness 2300kgf/mm2; used in control rods of nuclear reactors; can be prepared by heating HfO2 with lampblack under H2 at 1900°C–2300°C; used in crucible form for melting hafnium oxide, other oxides [KIR80] [HAW93] [CER91]

Physikalische Eigenschaften

Dark gray brittle solid, most refractory binary material known. Controls rods in nuclear reactors, crucible container for melting HfO and other oxides. 2 Corrosion resistant to liquid metals such as Nb, Ta, Mo, and W. Severe oxidation in air above 1100–1400°C and stable up to 2000°C in helium.

Verwenden

Hafnium carbide (HfC) with a melting point over 3890°C is a refractory binary compound. HfC and NbC can also be used as refractory coatings in nuclear reactors. The mixed carbide Ta4HfC5 possesses the highest melting point of any currently known compound at 4215°C.

Vorbereitung Methode

Hafnium carbide is a dark gray, brittle solid. It can be prepared by heating a mixture of the elements or by reacting hafnium tetrachloride with methane at 2100 C. Sufficient quantities of hafnium oxide or hafnium metal sponge are obtained during the large-scale production of pure zirconium for nuclear reactors. On an industrial scale, hafnium carbide can be produced from the hydrided hafnium sponge at 1500–1700 ℃ or from hafnium oxide at 2000–2200 ℃ by carburization in vacuo in the presence of hydrogen. The resulting carbide contains almost the theoretical quantity of carbon (6.30% °C) and a maximum of 0.1% free carbon (219). The hafnium carbide obtained is not a true stoichiometric compound as much as a solution of carbon at specific interstitial sites of a face-centered cubic hafnium lattice.
Hafnium carbide is inert to most reagents at room temperature but is dissolved by hydrofluoric acid solutions. Hafnium carbide reacts exothermally with halogens at 250–500 ℃to form hafnium tetrahalide, and to form hafnium oxide with oxygen above 500℃. In the presence of hydrogen, hafnium carbide slowly loses some of its carbon at higher temperatures.

Hafniumcarbid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Hafniumcarbid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 139)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12456 58
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282
alice@crovellbio.com China 8823 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
sales@tnjchem.com China 34572 58
Baoji Guokang Healthchem co.,ltd
+8615604608665 15604608665
dominicguo@gk-bio.com CHINA 9427 58
Zhuoer Chemical Co., Ltd
02120970332; +8613524231522
sales@zhuoerchem.com China 3015 58
Henan Alfa Chemical Co., Ltd
+8618339805032
alfa4@alfachem.cn China 12755 58
ShanDong Look Chemical Co.,Ltd.
+8617653113219
sales01@sdlookchemical.com China 2739 58
Alfa Chemistry
+1-5166625404
Info@alfa-chemistry.com United States 21317 58

12069-85-1(Hafniumcarbid)Verwandte Suche:


  • HAFNIUM CARBIDE
  • Hafnium carbide ceramics
  • hafnium(iv) carbide
  • HAFNIUM CARBIDE , 45 MICRON
  • Hafnium carbide, 99.5% (metals basis excluding Zr), Zr <1%
  • HAFNIUM(IV) CARBIDE, <1.25 MICRON
  • HAFNIUM(IV) CARBIDE -325MESH
  • Hafnium Carbide, -325 Mesh
  • Hafnium carbide/ 99+%
  • Hafnium monocarbide
  • Hafnium(IV) carbide <1.25 mum particle size
  • Hafnium carbide, 99.5% trace metals basis
  • Hafnium carbide powder (HfC)
  • um 99.8%Methanidylidynehafnium(1 Methanidylidynehafnium(1+)
  • hafnium,methane
  • Methanidylidynehafnium(1+)
  • Hafnium carbide HfC
  • Niobium Oxide (Nb2O5) Powder
  • Hafnium(IV) carbide, 99.8%
  • Hafnium(IV) carbide, <1.25 μm
  • Hafnium Carbide Micro powder
  • Cobalt Chromium (Co-Cr) Alloy Sputtering Targets
  • 12069-85-1
  • HfC2
  • HfC
  • CHf
  • Hafnium
  • Catalysis and Inorganic Chemistry
  • CarbidesChemical Synthesis
  • Catalysis and Inorganic Chemistry
  • Ceramics
  • Hafnium
  • Metal and Ceramic Science
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