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Fumaryl chloride

CAS No. 627-63-4
Chemical Name: Fumaryl chloride
Synonyms: tl189;TL 189;fumaryl;Fumarylchlorid;FumarylChoride;fumaroylchloride;FUMARYL CHLORIDE;Fumaroyl chloride;chloruredefumaryle;FUMARYL DICHLORIDE
CBNumber: CB1854022
Molecular Formula: C4H2Cl2O2
Formula Weight: 152.96
MOL File: 627-63-4.mol
Fumaryl chloride Property
Melting point : -2 °C
Boiling point : 161-164 °C(lit.)
density : 1.415 g/mL at 25 °C(lit.)
refractive index : n20/D 1.499(lit.)
Fp : 165 °F
storage temp. : Refrigerator (+4°C)
form : Liquid
color : Clear yellow
Water Solubility : decomposes
Sensitive : Moisture Sensitive
BRN : 1721342
CAS DataBase Reference: 627-63-4(CAS DataBase Reference)
NIST Chemistry Reference: Fumaryl chloride(627-63-4)
EPA Substance Registry System: 2-Butenedioyl dichloride, (2E)-(627-63-4)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : C
Risk Statements : 20/21/22-34-37-29-36/37-14
Safety Statements : 26-36/37/39-45-8-27
RIDADR : UN 1780 8/PG 2
WGK Germany : 3
RTECS : LT2800000
F : 21
TSCA : Yes
HazardClass : 8
PackingGroup : II
HS Code : 29171990
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P390 Absorb spillage to prevent material damage.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

Fumaryl chloride Chemical Properties,Usage,Production

Chemical Properties
Clear yellow liquid
General Description
A straw colored fuming liquid with a pungent odor. Flash point 165°F. Vapors irritate the eyes and mucous membranes. Corrosive to metals and tissue.
Reactivity Profile
Fumaryl chloride is incompatible with strong oxidizing agents, alcohols, amines and other bases. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Fumaryl chloride Preparation Products And Raw materials
Raw materials
Maleic anhydride Zinc chloride Fumaric acid Phosphorus pentachloride Phthaloyl dichloride Thionyl chloride
Preparation Products
Fumaryl chloride Suppliers      Global( 68)Suppliers     
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