ChemicalBook >> CAS DataBase List >>4'-Bromoacetophenone
4'-Bromoacetophenone
- CAS No.
- 99-90-1
- Chemical Name:
- 4'-Bromoacetophenone
- Synonyms
- 2-BROMO-1-(4-BROMOPHENYL)ETHAN-1-ONE;PBPB;1-(4-Bromophenyl)ethanone;p-Bromoacetophenone;P-BROMOPHENACYL BROMIDE;para-BROMOACETOPHENONE;p-BROMOACETOPHENONE pure;4-BroMobenz;ROMOACETOPHENONE;AKOS BBS-00000865
- CBNumber:
- CB2204949
- Molecular Formula:
- C8H7BrO
- Molecular Weight:
- 199.04
- MDL Number:
- MFCD00000105
- MOL File:
- 99-90-1.mol
- MSDS File:
- SDS
Last updated:2024-08-26 21:18:56
| Melting point | 108-110 °C(lit.) |
|---|---|
| Boiling point | 255 °C(lit.) |
| Density | 1.64 |
| refractive index | 1.5540 (estimate) |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | methanol: 0.1 g/mL, clear |
| form | Crystals or Crystalline Flakes |
| color | White to light yellow |
| Water Solubility | Soluble in Chloroform. Insoluble in water. |
| Merck | 14,1403 |
| BRN | 386015 |
| InChIKey | WYECURVXVYPVAT-UHFFFAOYSA-N |
| CAS DataBase Reference | 99-90-1(CAS DataBase Reference) |
| FDA UNII | 7NB3XRY0C6 |
| NIST Chemistry Reference | Ethanone, 1-(4-bromophenyl)-(99-90-1) |
| EPA Substance Registry System | Ethanone, 1-(4-bromophenyl)- (99-90-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | C,Xi,Xn | |||||||||
| Risk Statements | 34-36/38-42/43-36/37/38-22 | |||||||||
| Safety Statements | 26-36/37/39-45-22-36/37 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | AM6950000 | |||||||||
| F | 19-21 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29147090 | |||||||||
| NFPA 704 |
|
4'-Bromoacetophenone price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B56404 | 4′-Bromoacetophenone 98% | 99-90-1 | 25g | $32.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | B56404 | 4′-Bromoacetophenone 98% | 99-90-1 | 100g | $80.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21968 | 4′-Bromoacetophenone for synthesis | 99-90-1 | 25G | $43.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21968 | 4′-Bromoacetophenone for synthesis | 99-90-1 | 100G | $96.4 | 2024-03-01 | Buy |
| TCI Chemical | B0537 | 4'-Bromoacetophenone >98.0%(GC) | 99-90-1 | 25g | $33 | 2024-03-01 | Buy |
4'-Bromoacetophenone Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystals. soluble in alcohol, ether, glacial acetic acid, benzene, carbon disulfide and petroleum ether, insoluble in water. Easy to volatilize with water vapor.
Uses
4'-Bromoacetophenone is an important organic synthesis intermediate, widely used in synthetic medicine, pesticides, dyes, flavors and fragrances, perfumes, Intermediates of Liquid Crystals etc.
Uses
Labeled 4?-Bromoacetophenone possess activity against positive phototaxis of Chlamydomonas cells. A fundamental starting material for organic synthesis.
Preparation
4'-Bromoacetophenone is synthesized by the reaction of bromobenzene and acetic anhydride in the presence of aluminum trichloride.
Add bromobenzene and dry carbon disulfide into the reactor, put in powdered anhydrous aluminum trichloride, heat until it starts to reflux, stop heating, add acetic anhydride dropwise, and then reflux for 1 hour after adding, steam out carbon disulfide, and put it while it is still hot. The reactant was poured into the hydrochloric acid ice-water mixture, filtered to dryness, and distilled under reduced pressure to obtain p-bromoacetophenone.
Synthesis Reference(s)
The Journal of Organic Chemistry, 51, p. 5400, 1986 DOI: 10.1021/jo00376a064
Tetrahedron Letters, 26, p. 4657, 1985 DOI: 10.1016/S0040-4039(00)98778-1
Purification Methods
Crystallise it from EtOH, MeOH or from pet ether (b 80-100o). [Tanner J Org Chem 52 2142 1987, Beilstein 7 IV 647.]
4'-Bromoacetophenone Preparation Products And Raw materials
Raw materials
Preparation Products
ETHYL 4-ACETYLBENZOATE
4-Acetyl-2-fluorobiphenyl
1-(2-amino[1,1'-biphenyl]-4-yl)ethan-1-one
2,4'-Dibromoacetophenone
1-(2-NITRO-BIPHENYL-4-YL)-ETHANONE
1,3,5-Tris(4-bromophenyl)benzene
4-Bromomandelic acid
5-(4-BROMO-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE
ETHYL 2-AMINO-4-(4-BROMOPHENYL)-3-THIOPHENECARBOXYLATE
1,3,5-Tris(p-formylphenyl)benzene
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Global( 545)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 | 1022@dideu.com | China | 3878 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5873 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5895 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20291 | 58 |
| HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +8615383190639 | admin@86-ss.com | China | 1000 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21666 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2989 | 55 |
View Lastest Price from 4'-Bromoacetophenone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-09-26 | 4'-Bromoacetophenone
99-90-1
|
US $100.00-75.00 / ton | 1ton | 99% | 5000 | HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | |
 |
2024-09-23 | 4′-Bromoacetophenone
99-90-1
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
 |
2024-08-25 | 4'-Bromoacetophenone
99-90-1
|
US $0.00-0.00 / KG | 1KG | 99.0% | 1000KG | Shaanxi Dideu Medichem Co. Ltd |
-
- 4'-Bromoacetophenone
99-90-1
- US $100.00-75.00 / ton
- 99%
- HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
-
- 4′-Bromoacetophenone
99-90-1
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- 4'-Bromoacetophenone
99-90-1
- US $0.00-0.00 / KG
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
99-90-1(4'-Bromoacetophenone)Related Search:
DIBROMOACETOPHENONE-2,4
GSK-3BETA INHIBITOR VII
A,P-DIBROMOACETOPHENONE
ALPHA,4'-DIBROMOACETOPHENONE
ALPHA-4-DIBROMOACETOPHENONE
ALPHA,P-DIBROMOACETOPHENONE
AKOS BBS-00000865
4,OMEGA-DIBROMOACETOPHENONE
4-Bromophenaeyl bromide
p-Bromoacetophenones
4'-Bromoacetophenone 1-(4-Bromophenyl)ethanone 1-Acetyl-4-Bromobenzene
4-Bromoacetophenone99%
4-BromoacetophenoneForSynthesis
4-Bromoacetophenone,98%
4-Bromophenyl methyl ketone
p-Acetylbromobenzene
p-Bromphenyl methyl ketone
1-(4-Bromophenyl)ethane-1-one
Methyl 4-bromophenyl ketone
1-acytyl-4-bromobenzene
4′-Bromoacetophenone,1-Acetyl-4-bromobenzene
Of broMoacetophenone
1-(4-Bromophenyl)ethan-1-one, 1-(4-Bromophenyl)-1-oxoethane
The broMine acetophenone
1-(p-BroMophenyl)ethanone
1-BroMo-4-acetylbenzene
4-Acetyl-1-broMobenzene
4-AcetylbroMobenzene
4-Acetylphenyl BroMide
4-BroMobenz
1-(4-broMophenyl)-1-ethanone
OMEGA-BROMOACETOPHENONE
1-(4-bromophenyl)-ethanon
Acetophenone, 4'-bromo-
Ethanone,1-(4-bromophenyl)-
4''-BROMOACETOPHENONE 99%
1-Acetyl-4-bromobenzene
4'-Bromoacetophenone
4’-Bromoacetophene
4'-Bromoacetophenone, 98%, for synthesis
4'-Bromoacetophenone >
ROMOACETOPHENONE
p-Bromoacetophenone,98%
4-Bromoacetophenone pure, 98%
p-Bromoacetophenone
p-BROMOACETOPHENONE pure
2-BROMO-1-(4-BROMOPHENYL)ETHAN-1-ONE
PBPB
P-BROMOPHENACYL BROMIDE
para-BROMOACETOPHENONE
1-(4-Bromophenyl)ethanone
4'-Bromacetophenon
4'-Bromoacetophenone
4'-Bromacetophenon
99-90-1
Derivatization agents
Ketones
Luminescent Compounds/Detection