ChemicalBook >> CAS DataBase List >>Methyl (triphenylphosphoranylidene)acetate
Methyl (triphenylphosphoranylidene)acetate
- CAS No.
- 2605-67-6
- Chemical Name:
- Methyl (triphenylphosphoranylidene)acetate
- Synonyms
- (METHOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE;CMETPP;NSC 117573;NSC 407395;AURORA KA-874;idene)acetate;methyl 2-(triphenyl-;Aceticacid,(triphenylphosphoranylidene;Methyl (triphenylphosphoranylidene)acet;(Carbomethoxyethylene)triphenylphosphorane
- CBNumber:
- CB3248865
- Molecular Formula:
- C21H19O2P
- Molecular Weight:
- 334.35
- MDL Number:
- MFCD00008455
- MOL File:
- 2605-67-6.mol
- MSDS File:
- SDS
Last updated:2023-07-27 13:57:03
| Melting point | 168-172 °C (lit.) |
|---|---|
| Boiling point | 165～170℃ |
| Density | 1.17±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Acetonitrile (Slightly), Chloroform (Slightly) |
| form | Powder |
| color | White to off-white |
| Water Solubility | insoluble |
| Sensitive | Air Sensitive |
| BRN | 618430 |
| InChIKey | NTNUDYROPUKXNA-UHFFFAOYSA-N |
| CAS DataBase Reference | 2605-67-6(CAS DataBase Reference) |
| FDA UNII | D9MZ753Q8K |
| EPA Substance Registry System | Acetic acid, (triphenylphosphoranylidene)-, methyl ester (2605-67-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| Hazard Codes | T,Xi | |||||||||
| Risk Statements | 36/37/38-25 | |||||||||
| Safety Statements | 22-24/25-36-26 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Methyl (triphenylphosphoranylidene)acetate price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 157929 | Methyl (triphenylphosphoranylidene)acetate 98% | 2605-67-6 | 25g | $121 | 2024-03-01 | Buy |
| Sigma-Aldrich | 157929 | Methyl (triphenylphosphoranylidene)acetate 98% | 2605-67-6 | 100g | $240 | 2024-03-01 | Buy |
| TCI Chemical | T1363 | Methyl (Triphenylphosphoranylidene)acetate >98.0%(HPLC)(T) | 2605-67-6 | 25g | $72 | 2024-03-01 | Buy |
| TCI Chemical | T1363 | Methyl (Triphenylphosphoranylidene)acetate >98.0%(HPLC)(T) | 2605-67-6 | 100g | $240 | 2024-03-01 | Buy |
| Alfa Aesar | A14020 | (Methoxycarbonylmethylene)triphenylphosphorane, 98% | 2605-67-6 | 25g | $103 | 2024-03-01 | Buy |
Methyl (triphenylphosphoranylidene)acetate Chemical Properties,Uses,Production
Chemical Properties
white to off-white powder
Uses
Wittig reagent for the two-carbon homologation of aldehydes to α,β-unsaturated esters. Also used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine.
Uses
- (Methoxycarbonylmethylene)triphenylphosphorane is used in olefination reactions. Wittig reagent for the two-carbon homologation of aldehydes to α,β-unsaturated esters. it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates.
- used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine.
- It is used in the preparation of (triphenylphosphoranylidene)-ketene.
- The Wittig reaction we performed in class involved the reaction of 2-nitrobenzaldehyde (1) with methyl (triphenylphosphoranylidene) acetate (2) to produce methyl (2E)-3-(2-nitrophenyl) acrylate (3) with a triphenylphosphine oxide (4) side product, and took place in a silica gel matrix to ensure even product dispersion for chromatography.
Uses
(Methoxycarbonylmethylene)triphenylphosphorane is used in olefination reactions. Further, it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates. It is used in the preparation of (triphenylphosphoranylidene)-ketene.
Purification Methods
Crystallise it by dissolving in it AcOH and adding pet ether (b 40-50o) to give colourless plates. UV max (A 1mm ): 222nm (865) and 268nm (116) [Isler et al. Helv Chim Acta 40 1242 1957]. [Beilstein 16 IV 977.]
Methyl (triphenylphosphoranylidene)acetate Preparation Products And Raw materials
Global( 350)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8823 | 58 |
View Lastest Price from Methyl (triphenylphosphoranylidene)acetate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-01-14 | Methyl 2-(triphenylphosphoranylidene)acetate
2605-67-6
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-07-28 | Methyl (triphenylphosphoranylidene)acetate
2605-67-6
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2023-03-31 | Methyl (triphenylphosphoranylidene)acetate
2605-67-6
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Guanlang Biotechnology Co., Ltd. |
-
- Methyl 2-(triphenylphosphoranylidene)acetate
2605-67-6
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Methyl (triphenylphosphoranylidene)acetate
2605-67-6
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Methyl (triphenylphosphoranylidene)acetate
2605-67-6
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
2605-67-6(Methyl (triphenylphosphoranylidene)acetate)Related Search:
(TRIPHENYLPHOSPHORANYLIDENE)ACETIC ACID METHYL ESTER
AURORA KA-874
(CARBOMETHOXYMETHYLENE)TRIPHENYLPHOSPHORANE
METHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE
(2-METHOXY-2-OXOETHYLIDENE)TRIPHENYLPHOSPHORANE
ACETIC ACID, (TRIPHENYLPHOSPHORANYLIDENE)-, METHYL ESTER
Triphenylphosphinideneacetic acid methyl ester
Triphenylphosphoranylideneacetic acid methyl
(Carbomethoxyethylene)triphenylphosphorane
Methyl (triphenylphosphoranylidene)acetate,98%
Methyl (triphenylphosphoranylidene)acetate, 98% 25GR
Methoxycarbonylmethylene-triphenylphosphorane for synthesis
Acetic acid, 2-(triphenylphosphoranylidene)-, Methyl ester
NSC 117573
NSC 407395
(Carbomethoxymethylene)triphenylphosphorane
(Methoxycarbonylmethylene)triphenylphosphorane
(Triphenylphosphoranylidene)acetic Acid Methyl Ester
(Triphenyl-laMbda*5*-phosphanylidene)-acetic acid Methyl ester
Methyl 2-(triphenyl-$l^{5}-phosphanylidene)acetate
[(Methoxycarbonyl)methylene]triphenylphosphorane, (2-Methoxy-2-oxoethylidene)triphenylphosphorane
Methyl (triphenylphosphoranylidene)acet
Methyl (triphenylphosphoranylidene)acetateMethyl (triphenylphosphoranylidene)acetate
(triphenylphosphoranylidene)-aceticacimethylester
(Carbomethoxymethylene)triphenylphosphorane~Methyl (triphenylphosphoranylidene)acetate
carbmethoxy Methylene triphenyl Phosphorane
Methyl (triphenylphosphoranylidene)acetate 98%
Aceticacid,(triphenylphosphoranylidene
CMETPP
(Carbomethoxymethylene)triphenylphosphorane, (Methoxycarbonylmethylene)triphenylphosphorane
[(Methoxycarbonyl)methylene]triphenylphosphorane, 98 %
Methyl 2-tri(phenyl)phosphoranylideneacetate
2-(Triphenylphosphinidene)acetic acid methyl ester
Triphenyl(2-oxo-2-methoxyethylidene)phosphorane
methyl 2-(triphenyl-λ5-phosphanylidene)acetate
methyl 2-(triphenyl-λ^{5}-phosphanylidene)acetate
idene)acetate
Methoxyformylmethylene triphenyl phosphine
TIANFU-CHEM--Methyl (triphenylphosphoranylidene)acetate
methyl 2-(triphenyl-
(METHOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE
methyl (E)-2-(penta-1,3-dien-3-yldiphenyl-l5-phosphanylidene)acetate
Methyl (triphenylphosphoranylidene)acetate?New
methyl 2-(triphenyl-λ-phosphanylidene)acetate
2605-67-6
605-67-6
CH3O2CCHPC6H53
C21H19O2P
C6H53PCHCO2CH3
C6H53PCHCOOCH3
Wittig Reaction
Wittig & Horner-Emmons Reaction
C-C Bond Formation
Olefination
Synthetic Reagents
Wittig Reagents
Wittig Reagents
Synthetic Organic Chemistry
Wittig & Horner-Emmons Reaction
Wittig Reaction