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Methylene dithiocyanate

CAS No.
6317-18-6
Chemical Name:
Methylene dithiocyanate
Synonyms
MBT;METHYLENE BISTHIOCYANATE;RUBBER ACCELERATOR;v709;cp17879;WT 307B;proxelmb;Kilstain;Busan 110;Proxel MB
CBNumber:
CB6360991
Molecular Formula:
C3H2N2S2
Molecular Weight:
130.18
MDL Number:
MFCD00001833
MOL File:
6317-18-6.mol
Last updated:2024-03-25 15:20:08

Methylene dithiocyanate Properties

Melting point 104-106 °C(lit.)
Boiling point 285.2±23.0 °C(Predicted)
Density 1.492 (estimate)
refractive index 1.5300 (estimate)
Flash point >110°C
solubility very slightly in Methanol
form solid
color White to Light yellow to Light orange
Water Solubility Decomposes in water. Slightly soluble in organic solvents.
Stability Stable, but moisture sensitive. Reacts vigorously with strong bases, strong oxidizing agents. Reacts with water.
InChIKey JWZXKXIUSSIAMR-UHFFFAOYSA-N
CAS DataBase Reference 6317-18-6(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances METHYLENEBISTHIOCYANATE
FDA 21 CFR 176.300
EWG's Food Scores 3
FDA UNII K1QS9QOS1J
NIST Chemistry Reference Thiocyanic acid, methylene ester(6317-18-6)
EPA Substance Registry System Methylene dithiocyanate (6317-18-6)
Pesticides Freedom of Information Act (FOIA) Methylene bis(thiocyanate)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS07,GHS09
Signal word  Danger
Hazard statements  H301-H310-H314-H317-H400-H330
Precautionary statements  P260-P262-P264-P270-P272-P273-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P391-P405-P501-P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P501a
Hazard Codes  T,N,T+
Risk Statements  23/24/25-36/37-50-43-34-26-25
Safety Statements  26-28-36/37/39-45-61-28A
RIDADR  UN 2811 6.1/PG 2
WGK Germany  3
RTECS  XL1560000
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29309090
Toxicity LD50 oral in rat: 55mg/kg
NFPA 704
1
4 0

Methylene dithiocyanate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M1020 Methylene Dithiocyanate >99.0%(GC) 6317-18-6 25g $144 2024-03-01 Buy
TRC M304115 Methylene Dithiocyanate 6317-18-6 25g $70 2021-12-16 Buy
Usbiological 281667 Methylene Bis Thiocyanate 6317-18-6 25g $336 2021-12-16 Buy
Medical Isotopes, Inc. 41430 Methylene Dithiocyanate 6317-18-6 10g $575 2021-12-16 Buy
American Custom Chemicals Corporation CHM0030380 METHYLENE DITHIOCYANATE 95.00% 6317-18-6 1G $739.2 2021-12-16 Buy
Product number Packaging Price Buy
M1020 25g $144 Buy
M304115 25g $70 Buy
281667 25g $336 Buy
41430 10g $575 Buy
CHM0030380 1G $739.2 Buy

Methylene dithiocyanate Chemical Properties,Uses,Production

Chemical Properties

Colorless needle-like crystals or yellow crystalline powder. Melting point 102-104 ℃. Soluble in dioxane, dimethylformamide, slightly soluble in other organic solvents. The solubility in room temperature water is 2300 ppm. It is very sensitive to pH, and hydrolyzes quickly above pH=8.

Uses

Methylene Dithiocyanate emulsion is used as bactericide.

Preparation

Synthesis of methylene dithiocyanate: under pressure, add excess sodium thiocyanate (or sodium thiocyanate) and dichloromethane into the reaction kettle, start stirring, and heat up to 80-100°C at the same time. After the reaction is completed, dichloromethane is recovered, and the solid-liquid two phases are separated to obtain a crude methylene dithiocyanate.

Definition

ChEBI: Methylene dithiocyanate is a member of the class of thiocyanates that is methane in which two of the hycrogens have been replaced by thiocyanato groups. Used as a biocide for the control of various pathogens and algae in industrial water systems and as a fungicide for the control of surface moulds and sapstain fungi on wood. It has a role as a fungicide and an antibacterial agent.

General Description

Methylenebis(thiocyanate) appears as yellow to light orange-colored mass or yellow powder. (NTP, 1992)

Air & Water Reactions

May be sensitive to prolonged exposure to air. Decomposes in water (not vigorously) and more rapidly in boiling water.

Reactivity Profile

Methylenedithiocyanate reacts vigorously with strong bases and strong oxidizing agents such as hydrogen peroxide. Hydrolyzes slowly with water at boiling temperatures and reacts slowly and exothermically with aqueous acids .

Fire Hazard

Flash point data for Methylenedithiocyanate are not available; however, Methylenedithiocyanate is probably combustible.

Safety Profile

Poison by ingestion, intravenous, and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Methylene dithiocyanate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 371)Suppliers
Supplier Tel Email Country ProdList Advantage
Jinan Qinmu Fine Chemical Co.,Ltd.
+8618660799346 sales@qinmuchem.com China 1009 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Hunan aslsen technology co.,ltd
+8619313031929 aslsd@aslsen.com China 128 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Shanxi Naipu Import and Export Co.,Ltd
+86-13734021967 +8613734021967 kaia@neputrading.com China 1011 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58

View Lastest Price from Methylene dithiocyanate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methylenedithiocyanate pictures 2024-04-26 Methylenedithiocyanate
6317-18-6
US $0.00 / kg 1kg 99% 500mt Jinan Finer Chemical Co., Ltd
Methylene dithiocyanate pictures 2024-04-22 Methylene dithiocyanate
6317-18-6
US $0.00 / kg 1kg 99.9% 10tons/month Hunan aslsen technology co.,ltd
Dithiocyano methane pictures 2024-01-02 Dithiocyano methane
6317-18-6
US $50.00-1.00 / KG 1KG 99 g-kg-tons,free sample is available Henan Fengda Chemical Co., Ltd
Amerstat 282 Antiblu 3737 Busan 110 cp17879 Methane, dithiocyanato- Methylendirhodanid methylendirhodanid(czech) Methylendithiokyanat Methylene ester of Thiocyanic acid Methylene thiocyanate Methylenedirhodanid Methylenedirhodanide methylenethiocyanate N-948 Biocide Nalco D-1994 Nalfloc N 206 nalflocn206 Proxel MB proxelmb Slimicide MC Thiocyanicacid,methyleneester Tolcide MBT v709 DITHIOCYANATOMETHANATE DITHIOCYANATOMETHANE DITHIOCYANO METHANE METHYLENE DITHIOCYANATE METHYLENE BITHIOCYANATE MethyleneDithiocyanate~99% Methylenedithiocyanate98% CYTOX3522 Methylendithiocyanat 25) METHYLENE BIS THIOCYANATE Nalco 5793 Antiblu 3738 BasiMent 540 Bis(thiocyanato)Methane Kilstain Metasol T 10 Nalco D 2303 NSC 40464 Thiocyanic Acid C,C'-Methylene Ester WT 307B Dithiocyanatomethane Methylene Bisthiocyanate Methane dithiocyanate Methylene dithiocyate 2-Amino-4-methyl-5-benzamide thiazole Methylene Bis Thiocyanate (Mbt/Mtc) MethyleneDithiocyanate> MBT METHYLENE BISTHIOCYANATE RUBBER ACCELERATOR 6317-18-6 C3H2N2S2 Building Blocks Organic Building Blocks Thiocyanates/Isothiocyanates Sulfur Compounds