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Sodium chlorate

Description References

CAS No. 7775-09-9
Chemical Name: Sodium chlorate
Synonyms: asex;fall;defol;dervan;hibarc;oxycil;travex;desolet;granexo;kusatol
CBNumber: CB7378144
Molecular Formula: ClNaO3
Formula Weight: 106.44
MOL File: 7775-09-9.mol
Sodium chlorate Property
Melting point : 248-261 °C(lit.)
density : 2.49
storage temp. : room temp
PH: 5-7 (50g/l, H2O, 20℃)
Water Solubility : 1000 g/L (20 ºC)
Merck : 14,8598
Stability:: Stable. Mixtures of this material with organic fibrous or absorbent material and with a variety of other materials are potentially explosive. A full MSDS sheet must be consulted before use. Incompatible with strong reducing agents, organic materials, alcohols.
CAS DataBase Reference: 7775-09-9(CAS DataBase Reference)
EPA Substance Registry System: Chloric acid, sodium salt(7775-09-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : O,Xn,N
Risk Statements : 9-22-51/53
Safety Statements : 13-17-46-61
RIDADR : UN 1495 5.1/PG 2
WGK Germany : 2
RTECS : FO0525000
TSCA : Yes
HazardClass : 5.1
PackingGroup : II
Hazardous Substances Data: 7775-09-9(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H271 May cause fire or explosion; strong oxidiser Oxidising liquids;Oxidising solids Category 1 Danger P210, P220, P221, P280, P283,P306+P360, P371+P380+P375,P370+P378, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles/…
P273 Avoid release to the environment.
P283 Wear fire/flame resistant/retardant clothing.
P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P371+P380+P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Sodium chlorate Chemical Properties,Usage,Production

Description
Sodium chlorate (chemical formula: NAClO3) is an inorganic compound, appearing as white crystalline powder. It has an annual yield of several hundred million tons around the world. It has many applications. Its major commercial application is for the manufacture of chlorine dioxide which is used in bleaching of pulp. Sodium chlorate can also be used for the industrial manufacture of perchlorate compounds through electrolysis. It can also be used as a non-selective herbicide to control many kinds of plants such as morning glory, Canada thistle, Johnson grass and bamboo. In addition, it can also be used as a defoliant and desiccant. It is also used for the generation of chemical oxygen which is important for emergency oxygen generation in commercial aircraft. In industry, sodium chlorate is manufactured by the electrolysis of a hot sodium chloride solution. It is also useful for making inks, cosmetics, paper and leather.
References
https://pubchem.ncbi.nlm.nih.gov/compound/sodium_chlorate#section=Top
https://en.wikipedia.org/wiki/Sodium_chlorate
Chemical Properties
white crystals
Uses
It is oxidimetric reagent.
Uses
A sulfation biosynthesis inhibitor.
Definition
ChEBI: An inorganic sodium salt that has chlorate as the counter-ion. An oxidising agent, it is used for bleaching paper and as a herbicide. It is also used in the manufacture of dyes, explosives and matches.
General Description
Sodium chlorate in a water solution is a clear colorless liquid. Sodium chlorate is noncombustible but Sodium chlorate can accelerate the burning of surrounding combustible materials. This can easily occur if the material should dry out. Contact with strong sulfuric acid may cause fires or explosions.
Air & Water Reactions
Soluble in water.
Reactivity Profile
SODIUM CHLORATE decomposes upon heating forming O2; reacts with strong acids forming toxic and explosive ClO2; reacts with many substances [Handling Chemicals Safely 1980 p. 833]; metal chlorates are oxidants in the presence of strong acid; liberates explosive chlorine dioxide gas; heating a moist metal chlorate and a dibasic organic acid liberates chlorine dioxide and carbon dioxide; mixtures of perchlorates with sulfur or phosphorus are explosives [Bretherick 1979 p. 100]; mixtures of the chlorate with ammonium salts(ammonium thiosulfate), powdered metals, silicon, sulfur, or sulfides are readily ignited and potentially explosive [Bretherick 1979 p. 806]. A combination of finely divided aluminum with finely divided bromates(also chlorates and iodates) of barium, calcium, magnesium, potassium, sodium or zinc can explode by heat, percussion, and friction [Mellor 2:310 1946-47]. Sodium chlorate and arsenic trioxide form a spontaneously flammable mixture [Ellern 1968 p. 51]. Mixtures of organic material and more than 10% sodium chlorate are sufficiently combustible to be hazardous at low relative humidity. Mixtures of organic material such as charcoal, sugar, flour, or shellac and sodium chlorate may be ignited by friction or shock [Chem. Safety Data Sheet SD-42 1951].
Health Hazard
Contact causes irritation of eyes and skin. INGESTION: May cause nausea, vomiting, diarrhea, abdominal or gastric pain, dyspnea and other symptoms. The major cause of death from a lethal dose is acute renal failure.
Sodium chlorate Preparation Products And Raw materials
Raw materials
CHLORIC ACID DFASDFASD Sodium dichromate dihydrate Barium chloride dihydrate Sodium chloride LEAD(II) SULFATE Hydrochloric acid Sodium hydroxide Barium chloride Lead dioxide Graphite Sodium carbonate
Preparation Products
Vat Brown 3GR Sulphur Blue CV Pigment Green 18 COPPER(I) CYANIDE 1,1-Dimethylhydrazine Methyl anthranilate Vat Yellow 4 chlorinated sodium phosphate Platinum BLEACHEDSTARCH Shellac Copper(II) chloride dihydrate DIBENZANTHRONE 3-Phenoxy-benzaldehyde 4-(2-BENZOTHIAZOLYLDITHIO)MORPHOLINE 2-Furoic acid 1-Chloro anthraquinone Prussian Blue Manganese dioxide PERCHLORIC ACID Styrene oxide Phenethyl alcohol Chlorine dioxide 2-CHLORO-5-METHYLPHENOL Fumaric acid N,N-DIISOPROPYLBENZOTHIAZOLE-2-SULFENAMIDE 5-(TERT-BUTYL)-2-METHYLFURAN-3-CARBONYL CHLORIDE Sulfamethoxazole Ethyl maltol Potassium perchlorate N-Chlorosuccinimide Calcium iodate Azodicarbonamide Vat Brown 3 Sodium chlorite Calcium hypochlorite Chlorine dioxide,stable N-tert-Butyl-2-benzothiazolesulfenamide Ammonium ferric citrate
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