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Barium chloride

Soluble barium salt Chemical properties Uses Hazardous characteristics First-aid measure Solubility in water Toxicity Production method Hazards & Safety Information
Barium chloride
Barium chloride
CAS No.
10361-37-2
Chemical Name:
Barium chloride
Synonyms
BaCl2;ba0108e;Ba 0108E;sba0108e;SBA 0108E;NCI-C61074;Dichlorobarium;BARIUM CHLORIDE;bariumdichloride;BariumChlorideAcs
CBNumber:
CB8398703
Molecular Formula:
BaCl2
Formula Weight:
208.23
MOL File:
10361-37-2.mol

Barium chloride Properties

Melting point:
963 °C(lit.)
Boiling point:
1560°C
Density 
3.856 g/mL at 25 °C(lit.)
storage temp. 
2-8°C
solubility 
H2O: soluble
form 
beads
color 
White
PH
5-8 (50g/l, H2O, 20℃)
Water Solubility 
Soluble in water and methanol. Insoluble in acids, ethanol, acetone and ethyl acetate. Slightly soluble in nitric acid and hydrochloric acid.
Sensitive 
Hygroscopic
Merck 
14,971
Stability:
Stable.
CAS DataBase Reference
10361-37-2(CAS DataBase Reference)
NIST Chemistry Reference
Barium dichloride(10361-37-2)
EPA Substance Registry System
Barium chloride (BaCl2)(10361-37-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xi,Xn
Risk Statements  22-25-20-36/37/38-36/38-36
Safety Statements  45-36-26-36/37/39
RIDADR  UN 3264 8/PG 3
WGK Germany  1
RTECS  CQ8750000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
Hazardous Substances Data 10361-37-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P330 Rinse mouth.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Barium chloride price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 1.01716 Barium chloride 10361-37-2 1EA $241 2017-11-08 Buy
Sigma-Aldrich 1.01716 Barium chloride 10361-37-2 2EA $1252 2017-11-08 Buy
Alfa Aesar 10995 Barium chloride, anhydrous, 99.998% (metals basis) 10361-37-2 5g $34.7 2017-11-08 Buy
Alfa Aesar 10995 Barium chloride, anhydrous, 99.998% (metals basis) 10361-37-2 0.5g $20.6 2017-11-08 Buy
Strem Chemicals 93-5652 Barium chloride, anhydrous, 98+% 10361-37-2 100g $25 2017-11-27 Buy

Barium chloride Chemical Properties,Uses,Production

Soluble barium salt

Barium chloride is one of the most important soluble barium salts, it is also known as "salting barium", the formula is BaCl2, it has colorless monoclinic and colorless cubic two crystals, monoclinic crystal turns into cubic crystal at 962℃. At room temperature it is white lustrous monoclinic crystal, odorless, bitter and salty. It is soluble in water, insoluble in acetone, ethanol and ether, slightly soluble in acid, sulfuric acid. Crystallization from aqueous solution of barium chloride often contains two crystal water. When heated to 113℃, it loses crystal water and becomes anhydrous barium chloride, it is white powder. It can be used for identification and separation of SO42-ions, purify the brine water, mainly used for the manufacture of barium salts and pigments, it can also be used as hard water softener, wool and leather industry mordant, pesticides for controlling plant pests. Preparation of industrial barium chloride is mainly used barite as material which containing high components of barium sulfate barite, coal and calcium chloride is mixed, and calcined to get barium chloride, reaction is as follows: BaSO4 + 4C + CaCl2 → BaCl2 + CaS + 4CO ↑.

Chemical properties

It is colorless monoclinic crystal. (Α type) it is soluble in water, slightly soluble in hydrochloric acid, nitric acid, very slightly soluble in alcohol.

Uses

(1) Barium chloride is mainly used for heat treatment of metals, barium salt manufacturing, electronic instruments, and used as water softener.
(2) It can be used as dehydrating agent and analysis reagents, it is used for machining heat treatment Jing, see other barium chloride dihydrate.
(3) Calibration instruments and devices, evaluation methodology, quality assurance/quality control.

Hazardous characteristics

Barium chloride is noncombustible. It is highly toxic. When contacts boron trifluoride, violent reaction can occur. Swallowed or inhaled can cause poisoning, it is mainly through the respiratory tract and digestive tract to invade the human body, it will cause drooling and burning esophagus, stomach pain, cramps, nausea, vomiting, diarrhea, high blood pressure, no law firm pulse, cramps, a lot of cold sweat, weak muscle strength, gait, vision and speech problems, difficulty breathing, dizziness, tinnitus, consciousness usually clear. In severe cases, it can cause sudden death. Barium ions can cause muscle stimulant, then gradually transforms into paralysis. Rat oral LD50150mg/kg, mouse peritoneal LD5054mg/kg, rats are intravenously LD5020mg/kg, orally in dog LD5090mg/kg.

First-aid measure

When skin contacts it, rinsing with water, then thoroughly washing with soap. When eye contacts, flushing with water. So that patients inhaled dust should leave from the contaminated area, move to fresh air place, rest and keep warm, if necessary, artificial respiration should be taken, seek medical attention. When swallowed, immediately rinse the mouth, gastric lavage should be taken with warm water or 5% sodium hydrosulfite for catharsis. Even swallows more than 6h, gastric lavage is also necessary. Intravenous infusion is slowly taken with 1% sodium sulfate of 500ml~1 000ml, intravenous injection can also be taken with 10% sodium thiosulfate of 10ml~20ml. Potassium and symptomatic treatment should be carried out.
Soluble barium salts of barium chloride is rapidly absorbed, so the symptoms develop rapidly, at any time cardiac arrest or respiratory muscle paralysis can cause death. Therefore, first aid must be against the clock.

Solubility in water

Grams which dissolves in per 100 ml of water at different temperatures (℃):
31.2g/0 ℃; 33.5g/10 ℃; 35.8g/20 ℃; 38.1g/30 ℃; 40.8g/40 ℃
46.2g/60 ℃; 52.5g/80 ℃; 55.8g/90 ℃; 59.4g/100 ℃.

Toxicity

See barium chloride dihydrate.

Production method

Barium chloride dihydrate is heated to above 150℃ by dehydration to obtain anhydrous barium chloride products. its
BaCl2 • 2H2O [△] → BaCl2 + 2H2O

Hazards & Safety Information

Category: toxic substances.
Toxicity grading: highly toxic.
Acute oral toxicity-rat LD50: 118 mg/kg; Oral-Mouse LD50: 150 mg/kg
Flammability hazard characteristics: It is non-combustible; fire and toxic chloride fumes containing barium compounds.
Storage characteristics: Treasury ventilation low-temperature drying; it should be stored separately with food additives.
Extinguishing agent: Water, carbon dioxide, dry, sandy soil.
Professional Standards: TLV-TWA 0.5 mg (barium)/cubic meter; STEL 1.5 mg (barium)/cubic meter.

Chemical Properties

White Crystalline Powder

Definition

ChEBI: The inorganic dichloride salt of barium.

General Description

Any of a variety of substances that contain barium. Most are whitish colored crystalline solids. They tend to be soluble in water and denser than water. They may be toxic by inhalation or possibly skin absorption. They are often used to make other chemicals.

Air & Water Reactions

Water soluble.

Reactivity Profile

BARIUM CHLORIDE may react violently with BrF3 and 2-furan percarboxylic acid in its anhydrous form.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Barium chloride Preparation Products And Raw materials

Raw materials

Preparation Products


Barium chloride Suppliers

Global( 201)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 512 57
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96820 76
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30309 84
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3434 62
BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807
010-87653215;0757-86311057;021-55236763 sales@hwrkchemical.com China 15553 55
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44192 61
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10090 60
Secco work (Beijing) chemical technology co., LTD 010-69755668;
010-69755668 1139670422@qq.com China 3546 54
Syntechem Co.,Ltd Please Email
E-Mail Inquiry info@syntechem.com China 13094 57
Sinopharm Chemical Reagent Co,Ltd. 86-21-63210123
86-21-63290778 86-21-63218885 sj_scrc@sinopharm.com China 9977 79

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