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TERT-BUTYL ISOCYANIDE

TERT-BUTYL ISOCYANIDE Structure
TERT-BUTYL ISOCYANIDE structure
CAS No.
7188-38-7
Chemical Name:
TERT-BUTYL ISOCYANIDE
Synonyms
2-ISOCYANO-2-METHYL-PROPANE;TBIN;Propane, 2-isocyano-2-methyl-;T-BUTYLISOCYANIDE;TERT-BUTYL ISONITRILE;2-methylpropyl isocyanide;(CH3)3CNC;TERT-BUTYL ISOCYANIDE;2-methylpropyl cyanide;t-Butylisocyanide,min.98%
CBNumber:
CB8121846
Molecular Formula:
C5H9N
Molecular Weight:
83.13
MDL Number:
MFCD00000002
MOL File:
7188-38-7.mol
MSDS File:
SDS
Last updated:2024-03-28 13:39:29
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TERT-BUTYL ISOCYANIDE Properties

Melting point 148-150 °C
Boiling point 91 °C(lit.)
Density 0.735 g/mL at 25 °C(lit.)
refractive index n20/D 1.376(lit.)
Flash point -2 °C
storage temp. Inert atmosphere,2-8°C
solubility Soluble in organic solvents such as ethanol, methanol, ether, toluene and dichloromethane.
form liquid
color colorless
Specific Gravity 0.735
BRN 1903156
Exposure limits NIOSH: IDLH 25 mg/m3
Stability store cold
CAS DataBase Reference 7188-38-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 22S4Z857K3

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06
Signal word  Danger
Hazard statements  H225-H330
Precautionary statements  P210-P304+P340+P310
Hazard Codes  F,T
Risk Statements  11-23-2017/11/23
Safety Statements  16-45
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  EQ7102500
HazardClass  3
PackingGroup  II
HS Code  29299090
NFPA 704
3
4 0

TERT-BUTYL ISOCYANIDE price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 260630 tert-Butyl isocyanide 98% 7188-38-7 1g $56.6 2024-03-01 Buy
Sigma-Aldrich 260630 tert-Butyl isocyanide 98% 7188-38-7 5g $173 2024-03-01 Buy
TCI Chemical B1274 tert-Butyl Isocyanide >95.0%(GC) 7188-38-7 5mL $138 2024-03-01 Buy
TCI Chemical B1274 tert-Butyl Isocyanide >95.0%(GC) 7188-38-7 25mL $476 2024-03-01 Buy
Alfa Aesar L19747 tert-Butyl isocyanide 98% 7188-38-7 1g $52.1 2024-03-01 Buy
Product number Packaging Price Buy
260630 1g $56.6 Buy
260630 5g $173 Buy
B1274 5mL $138 Buy
B1274 25mL $476 Buy
L19747 1g $52.1 Buy

TERT-BUTYL ISOCYANIDE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

tert-Butyl isocyanide is used in a tin-free procedure for alkyl radical reactions in the presence of a free-radical initiator. It is a useful intermediate in multicomponent reactions. It is also used in the synthesis of coumarines, 4H-chromenes, isoxazolines and to trap 2-cyclopropylidene-1,3-diones.

Preparation

Phosgene (1.0 kg, 10.1 mol) was delivered through a wide tube into a stirred solution of N-t-butylformamide (1.01 kg, 10.0 mol) in triethylamine (1.30 kg) and o-dichlorobenzene (7.0 L) in a flask fitted with a reflux condenser charged with a freezing mixture of ice and salt (-20 C°). Water was added, the layers were separated, and the non-aqueous layer was dried over anhydrous potassium carbonate or magnesium sulfate and fractionated; bp 90–92 C°/750 mmHg; yield: 681 g (82%).

Preparation

CAUTION: Use a well-ventilated hood and observe all precautions when using hydrogen cyanide.
To a 1-1, stainless steel Hoke pressure cylinder in a well-ventilated hood is added 196 gm (3.5 moles) of isobutene, 95 gm (3.5 moles) of hydrogen cyanide, and 100 gm (0.7 mole) or cuprous bromide. The cylinder is closed, shaken for 15 hr at 70°C, cooled to room temperature, and vented cautiously in the hood, and the viscous residue is poured slowly into aqueous potassium cyanide (260 gm in 100 ml of water) to decompose the cuprous complex, liberating an organic layer. The organic layer is separated, dried, and distilled under reduced pressure to afford 97 gm, b.p. 60-63°C (314 mm Hg), ng 1.3749, IR 2143 s, 1472 m, 1368 m, 1230 m, 1208 m, 855 w c m - 1; yield, 33% based on starting isobutylene; 16% based on CuBr.
Preparation of t-Butyl Isonitrile

General Description

Carbon dative bond formation by tert-butyl isocyanide on the germanium (100) surface has been reported. It also forms complexes with metals and inserts into metal-carbon bonds to form iminoacyls.

TERT-BUTYL ISOCYANIDE Preparation Products And Raw materials

Raw materials

Benzyltriethylammonium chloride Chloroform Dichloromethane tert-Butylamine

Preparation Products

N-(tert-butyl)-3-nitrobenzamide 2H-1,2,4-Benzothiadiazine 1,1-dioxide

TERT-BUTYL ISOCYANIDE Suppliers

Global( 181)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Jinan Carbotang Biotech Co.,Ltd. 		+8615866703830 figo.gao@foxmail.com China 6992 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Nanjing jinheyou Trading Co., Ltd. 		15705188088 admin@jheyou.com CHINA 1268 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49390 58
Supplier Advantage
Henan Fengda Chemical Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Jinan Carbotang Biotech Co.,Ltd. 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Nanjing jinheyou Trading Co., Ltd. 		58
CONIER CHEM AND PHARMA LIMITED 		58

View Lastest Price from TERT-BUTYL ISOCYANIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TERT-BUTYL ISOCYANIDE pictures 2024-03-29 TERT-BUTYL ISOCYANIDE
7188-38-7
 US $6.00-0.20 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
TERT-BUTYL ISOCYANIDE pictures 2022-09-12 TERT-BUTYL ISOCYANIDE
7188-38-7
 US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
TERT-BUTYL ISOCYANIDE pictures 2021-07-13 TERT-BUTYL ISOCYANIDE
7188-38-7
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

TERT-BUTYL ISOCYANIDE Spectrum

TERT-BUTYL ISOCYANIDE(7188-38-7)MSTERT-BUTYL ISOCYANIDE(7188-38-7)1HNMRTERT-BUTYL ISOCYANIDE(7188-38-7)13CNMRTERT-BUTYL ISOCYANIDE(7188-38-7)IR1TERT-BUTYL ISOCYANIDE(7188-38-7)Raman

7188-38-7(TERT-BUTYL ISOCYANIDE)Related Search:

4-Fluorophenyl isocyanate Ethyl isocyanate Propyl isocyanate 3-Methylindole tert-Butyl ethyl ether
N,N'-Diphenylurea 2-ETHYLPHENYL ISOCYANATE PROPYL ISOTHIOCYANATE Isoquinoline-1-carboxylic acid Hexyl isocyanate
Chlorosulfonyl isocyanate ISOCYANIC ACID 2-Isocyanatoethyl Acrylate Isothiazolinones m-Tolyl isocyanate
Butyl isocyanate ALLYL ISOCYANATE Isopropyl isocyanate

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TERT-BUTYL ISOCYANIDE (CH3)3CNC 2-isocyano-2-methyl-propan 2-Methyl-2-isocyanopropane Propane,2-isocyano-2-methyl- t-Butylisocyanide,min.98% t-Butylisocyanide, min. 98% tert-Butyl isocyanide,97% tert-Butyl isocyanide ,98% tert-Butyl isocyanide 98% tert-Butyl Isocyanide, 95.0%(GC) 2-methylpropyl cyanide Propane,2-Isocyanato-2-methylpropane tert-Butyl Isocyanide > 2-ISOCYANO-2-METHYL-PROPANE TERT-BUTYL ISONITRILE T-BUTYLISOCYANIDE Propane, 2-isocyano-2-methyl- TBIN 2-methylpropyl isocyanide tert-Butyl isocyanide (6CI, 7CI, 8CI) 7188-38-7 ISOCYANATE Isocyanides Nitrogen Compounds Organic Building Blocks Building Blocks organic compound Isocyanides Nitrogen Compounds Organic Building Blocks