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p-Toluidine

CAS No. 106-49-0
Chemical Name: p-Toluidine
Synonyms: ci37107;c.i.37107;tolyamine;NSC 15350;р-Touidin;p-Toluidin;Tolylamine;р-Touidine;NSC 114040;P-TOLUIDINE
CBNumber: CB8381150
Molecular Formula: C7H9N
Formula Weight: 107.15
MOL File: 106-49-0.mol
p-Toluidine Property
Melting point : 41-46 °C(lit.)
Boiling point : 200 °C(lit.)
density : 0.973 g/mL at 25 °C(lit.)
vapor density : 3.9 (vs air)
vapor pressure : 0.26 mm Hg ( 25 °C)
refractive index : 1.5636
Fp : 192 °F
storage temp. : 2-8°C
solubility : Soluble in ethanol, pyridine, diethyl ether, acetone, carbon tetrachloride, methanol, carbon disulfide, oils and dilute acids.
form : powder
pka: 5.08(at 25℃)
color : tan to brown
explosive limit: 6.6%
Water Solubility : 1.1 g/100 mL
Sensitive : Air & Light Sensitive
Merck : 14,9536
BRN : 471281
Stability:: Stable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference: 106-49-0(CAS DataBase Reference)
NIST Chemistry Reference: p-Toluidine(106-49-0)
EPA Substance Registry System: Benzenamine, 4-methyl-(106-49-0)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : T,N
Risk Statements : 23/24/25-36-40-43-50
Safety Statements : 28-36/37-45-61-28A
RIDADR : UN 3451 6.1/PG 2
WGK Germany : 2
RTECS : XU3150000
F : 8-23
TSCA : Yes
HazardClass : 6.1
PackingGroup : II
HS Code : 38220000
Hazardous Substances Data: 106-49-0(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

p-Toluidine Chemical Properties,Usage,Production

Chemical Properties
white lustrous plates or leaflets with an amine odour
Definition
ChEBI: An aminotoluene in which the amino substituent is para to the methyl group.
General Description
Colorless solid. Melting point 44°C (111°F). Specific gravity 1.046. Vapor heavier than air. Produces toxic oxides of nitrogen during combustion. May be absorbed through the skin. Used in dyes, and in organic chemical manufacturing.
Air & Water Reactions
Very slightly soluble in water.
Reactivity Profile
p-Toluidine neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides. Can react vigorously with oxidizing reagents. Emits very toxic fumes of oxides of nitrogen when heated to decomposition. Hypergolic reaction with red fuming nitric acid [Kit and Evered, 1960, p. 239, 242].
Health Hazard
Absorption of toxic quantities by any route causes cyanosis (blue discoloration of lips, nails, skin); nausea, vomiting, and coma may follow. Repeated inhalation of low concentrations may cause pallor, low-grade secondary anemia, fatigability, and loss of appetite. Contact with eyes causes irritation.
Fire Hazard
Special Hazards of Combustion Products: Toxic and flammable vapors may form in fire.
p-Toluidine Preparation Products And Raw materials
Raw materials
SODIUM SULPHIDE HYDRATE Sodium sulfide 4-Nitrotoluene
Preparation Products
4-Aminotoluene-3-sulfonic acid 5-Methyl-2-phenyl-1,2-dihydropyrazol-3-one 6-Quinolinylmethanol 4-Aminobenzotrifluoride 1-(4-METHYLPHENYL)PIPERAZINE Acid Green 25 1R-cis-Permethrinic acid Pigment Red 122 6-Quinolinecarbaldehyde 4-Fluorobenzotrifluoride 4-Bromotoluene 5-Amino-2-methylbenzenesulfonic acid N-(3-Hydroxyphenyl)-4-toluidine p-Fluorotoluene 3-Nitrotoluene ACID BLUE 25 2-Nitro-p-cresol 3,5-dinitrotoluene 2-(4-Aminophenyl)-6-methyl-1,3-benzothiazole-7-sulfonic acid 4-Methyl-2-nitroaniline FUCHSIN BASIC 4-Chlorotoluene
p-Toluidine Suppliers      Global( 208)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shanghai Excellent Chemical Co., Ltd. 0086-21-33559231; 018964673308 qq48685515;Skype: excellentchem
0086-21-33559231 sales@excellentchem.com China 2111 59
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 25125 65
Tianjin Zhongxin Chemtech Co., Ltd. 86(0)22-89880739
86(0)22-89880739 ext 8030 / 86-22-66880086 sales@tjzxchem.com China 554 60
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96831 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30314 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3437 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44197 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 10816 60
 
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